The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
~Allanite.~--Allanite, or Orthite, as it is often called, is a mineral
of the epidote family, containing rare earths. The general formula for
Epidote is H₂O,4R´´O,3R´´´´₂O₃,6SiO₂, where R´´ is a divalent and R´´´ a
trivalent metal, or vicarious series of metals. In the case of Allanite,
R´´ = (Fe´´,Ca), R´´´ = (Al,Fe´´´,E), where E stands for metals of the
cerium and yttrium groups (Engström’s formula). Groth formulates it as
a basic salt, R´´´₃(OH)R´´₂Si₃O₁₂, of the acid H₁₂Si₃O₁₂ (= 3H₄SiO₄).
Crystals are fairly common, but the mineral usually occurs massive or in
rounded grains.
Crystals--Monoclinic, holosymmetric; _a_ : _b_ : _c_ = 1·5509 : 1 :
1·7691, β = 64° 59´.
Common forms--Ortho- and basal pinakoids _a_ {100} and _c_ {001}; _m_
{110} and other prisms, _e_ {101} and other hemi-ortho-prisms, _o_
{011}, _d_ {111} and other hemi-pyramids.
Angles, (100) ∧ (110) = 54° 34´; (001) ∧ (101) = 63° 24´; (001) ∧
(011) = 58° 3´.
Tabular, parallel to _a_, or long and slender by elongation parallel
to axis _b_.
Birefringence weak, variable. Refraction strong. Colour brown to
brownish-black; almost opaque. In flakes very strongly pleochroic, the
colours for light parallel to the three vibration directions ~c~, ~b~
and ~a~ being brownish-yellow, reddish-brown, and greenish-brown
respectively.
Brittle. Hardness 5¹⁄₂-6; sp. gr. 3·5-4·2.
On heating, allanite becomes amorphous and isotropic with increase of
specific gravity (cf. Gadolinite). Before the blowpipe it loses water,
and melts to a black magnetic glass, many varieties phosphorescing
strongly (_vide supra_). With hydrochloric acid it gelatinises, unless
previously heated strongly, in which case it is not attacked.
Analyses show that the rare earth content varies considerably
(vicariously as regards ferric iron and aluminium), ceria earths varying
from 3·6 to 51·1 per cent. and yttria earths from traces up to 4·7 per
cent.[37] Thoria is usually present, 0 to 3·5 per cent. In 1909
Fromme[38] found small quantities of beryllia in the mineral, and in
1911 Meyer[39] found amounts of scandium oxide up to 1 per cent. It
contains traces of uranium, and is weakly radioactive. Ramsay, Collie
and Travers found no helium (1895), but in 1905 Strutt found radium in
it, so that the presence of helium seems _a priori_ probable.
[37] _Vide_ Schilling, pp. 70-75 for analyses of this mineral.
[38] Fromme, _Tsch. Min. Mitt._ 1909, ~28~.
[39] Meyer, _Sitzungsber. königl. Akad. Wiss. Berlin_, 1911, 379.
Many varieties of the mineral are known, differing in habit, colour,
water content, specific gravity, etc., and the percentage composition
varies very much by reason of vicarious replacement of the bases.
Goldschmidt[40] has found ‘Epidote-orthites’ which are isomorphous
mixtures of orthite with an iron epidote; he concludes that most
orthites are probably similar solid solutions, and in this way accounts
to a large extent for the varying composition.
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