The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
In 1907 Hussak[115] published a paper in which he showed that the
mineral named after him was not a new species at all, but a xenotime of
prismatic habit. Analyses made at his request by Florence in Brazil, G.
T. Prior in London, and Tschernik in St. Petersburg, confirmed the
original values given by Gorceix (sulphur trioxide up to 0·25 per
cent.). He mentions Brögger’s analysis of the Norwegian specimen in
which Kraus and Reitinger had found 2-3 per cent. of sulphur trioxide,
but in which Brögger found none. He explains the results of Kraus and
Reitinger as due to the addition of barium chloride to the acidified
solution of the carbonate fusion of the mineral, by which barium
phosphate was precipitated; this was dried and weighed as barium
sulphate. Rösler’s tests are declared doubtful; xenotime is not a widely
spread rock constituent, the mineral in question being really zircon.
[115] _Centr. Min._ 1907, 533.
In face of these results, there can be little doubt that the name
‘hussakite’ is unnecessary and undesirable, since the mineral to which
it was applied is proved to be xenotime.
* * * * *
In the alphabetical list, particulars of the following rare earth
phosphates will be found:
_Castelnaudite_, a variety of xenotime containing zirconia.
_Churchite_ and _Rhabdophane_ (Scovillite), hydrated phosphates.
_Gorceixite_, an alumino-phosphate of alkaline and ceria earths.
_Retzian_, an hydrated arsenate of manganese, calcium and rare earth
metals.
(_b_) THE HALIDES
~Yttrocerite.~--This mineral is a fluoride of calcium and rare earth
metals, with water. A recent analysis by Tschernik[116] gives the
formula Ce₂F₆,2Y₂F₆,9CaF₂,2H₂O. Putting the rare earth metals together,
this gives 6RF₃,9CaF₂,2H₂O, or R₂Ca₃F₁₂,²⁄₃H₂O. Yttrocerite is of
interest since it was probably in the analysis of this mineral by the
discoverers, Berzelius and Gahn, that the double sulphate method of
separating the yttria from the ceria earths was first employed[117]
(_vide_ p. 156).
[116] _Abstr. Chem. Soc._ 1907, ~92~, ii. 362.
[117] _Schweigg. J._ 1816, ~16~, 244.
It is found only massive or granular. Colour usually white to
violet-blue, sometimes reddish-brown. Hardness 4¹⁄₂; sp. gr. 3·45.
Infusible, but loses colour before the blowpipe. When powdered, it
dissolves completely in boiling hydrochloric acid, and readily in
sulphuric acid with evolution of heat. It has been found at various
localities in Scandinavia.
~Yttrofluorite.~[118]--This is a fluoride of varying composition, very
similar to yttrocerite, but characterised by the absence of water, and
the very small ceria content (1·7 per cent.). It is thus a fluoride of
calcium and the yttrium metals.
[118] T. Vogt, _Centr. Min._ 1911, 373.
Cubic, with poor octahedral cleavage. Colour, yellow to brown and
yellowish-green; transparent to translucent, bleached by weathering.
Very brittle. Hardness 4¹⁄₂; sp. gr. 3·54-3·56.
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