The Rare Earths: Their Occurrence, Chemistry, and TechnologyLevy, Stanley Isaac
Science
The Rare Earths: Their Occurrence, Chemistry, and Technology
Levy, Stanley Isaac
Rare earths
The history of the rare earth minerals begins in the year 1751, when the
Swedish mineralogist Cronstedt described a new mineral, which he had
found intimately mixed with chalcopyrite[1] in the quarry of Bastnäs,
near Ryddarhyttan, in the province of Westmannland, Sweden. Cronstedt
gave the mineral the name Tung-sten (heavy stone); but as the name
Tenn-spat (heavy spar, or heavy mineral) had already been selected by
Wallerius (1747) for a new species from Bohemia, believed to contain
tin, the choice was not a happy one. More than fifty years after its
discovery, a new earth, now known as ceria, was isolated from
Cronstedt’s mineral, for which at the same time the name Cerite was
proposed.[2] Meanwhile, however, the Finnish chemist Johann Gadolin had
observed, in the year 1794, a new earth in a mineral discovered by
Arrhenius at Ytterby in Sweden in 1788; he called the new oxide
Ytterbia, and the mineral in which he observed it, Ytterbite. The
discovery was confirmed in 1797 by Ekeberg, who suggested the names
Yttria and Gadolinite for the oxide and mineral respectively; these
names were accepted by Klaproth, and soon came into general use.[3]
Whilst then Cerite was the first of the rare earth minerals to be
discovered, it was in Gadolinite that new elements were first
recognised, and the chemistry of the rare earths began in 1794 with
Gadolin’s observation.
[1] Chalcopyrite, or Copper pyrites, is a mixed sulphide of iron and
copper, of the approximate formula CuFeS₂.
[2] For the history of the name Tungsten, see under the mineral
Cerite, Ch. II.
[3] The history of these names will be found somewhat more fully under
Gadolinite, Ch. II.
During the nineteenth century a considerable number of rare earth
minerals was discovered and analysed; the quantities of the minerals
observed, however, were so small that the name ‘Rare earths,’ applied to
the new oxides found, was in every sense justified. Until the year 1885,
though by that time the scientific interest of the group had been fully
demonstrated by the discovery of several new elements, it was supposed
that the minerals were almost entirely confined to a few scattered
localities in Scandinavia and the Ural mountains. In that year Dr. Auer
von Welsbach announced his application of the rare earths to the
manufacture of incandescent mantles. Immediately there was a great
demand for raw material for the preparation of thoria and ceria. The
agents of the Welsbach Company visited all the important mining centres
of Europe and America, intent on a search which shortly made it clear
that the metals of the so-called ‘rare earths’ are really quite widely
distributed in nature. The chief commercial deposits are the monazite
sands of the Carolinas, the Idaho basin, and Brazil, the gem-gravels of
Ceylon, and the remarkable deposits of gadolinite and allied minerals at
Barringer Hill in Texas.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account