The reaction between manganese dioxide and potassium permanganateHopkins, Arthur John
Science
The reaction between manganese dioxide and potassium permanganate
Hopkins, Arthur John
Manganese; Thesis (Ph. D.)
The variations from these proportions occurring in subsequent
experiments are noted in the table giving the summary of the results.
Usually about 150 m.g. of manganese dioxide were used and the solutions
in the three flasks were brought to the same volume by addition of
distilled water.
Experiment No. I
Flask No. I Manganese dioxide 150 m.g.
N/10 nitric acid 14.28 c.c.
[= Mn. in KMnO₄ in No. II or No. III]
Water, 27.12 c.c.
[Total solution = 41.40 c.c.]
Flask No. II
Potassium permanganate, 20 c.c. = 112.48 m.g. KMnO₄.
N/10 nitric acid 7.14 c.c. [= K in KMnO₄]
Water, 14.26 c.c.
[Total solution = 41.40 c.c.]
Flask No. III
Potassium permanganate, 20 c.c. = 112.48 m.g. KMnO₄.
N/10 nitric acid 21.40 c.c. [= K + Mn in KMnO₄]
Manganese dioxide 150 m.g.
The nitric acid in No. I is calculated to be the same as that remaining
free after the potassium of the permanganate in No. III has been
neutralized. It will be clear that the quantities of free nitric acid
are the same in flask No. I and in flask No. III provided the potassium
of the permanganate is appropriated by the nitric acid. Moreover each
flask contains the same quantity of manganese dioxide and the volume of
the liquid is the same in both.
On the other hand flask No. III contains permanganic acid. This
arrangement was selected in order to determine how far the evolution
of oxygen was influenced by the action of nitric acid on the manganese
dioxide or by the spontaneous decomposition of permanganic acid. It
was thought that if more oxygen should be obtained from flask No. III
containing a mixture of permanganate, manganese dioxide and nitric
acid, than from mixtures No. I and No. II, the larger volume must be
due to the reduction of the permanganate by the manganese oxide.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account