The Science of BrickmakingHarris, George Frederick
Science
The Science of Brickmaking
Harris, George Frederick
Brickmaking -- Handbooks, manuals, etc.
CaO, lime, instead of calcium oxide.
Al2O3, alumina, instead of aluminium trioxide.
SiO2, silica, instead of silicon dioxide.
Na2O, soda, instead of sodium oxide.
K2O, potash, instead of potassium oxide.
MgO, magnesia, instead of magnesium oxide.
In _analysing_ a body, the first step consists in determining the
nature of the elementary substances contained therein. That may be
accomplished in the _dry way_ by means of the blowpipe and accessories,
as explained in the last chapter. Such an examination, as previously
remarked, is known as a _qualitative_ analysis. Or, it may be
accomplished in the _wet way_ by ordinary chemical examination. The
next step is to determine the amount of the constituents present, and
that is known as a _quantitative_ analysis. In making a qualitative
analysis, the chemist is assisted by the knowledge that certain basic
substances and certain acids produce peculiar phenomena in the
presence of known substances or preparations termed _reagents_.
There is a great difference between a _chemical compound_ and a simple
_mixture_ of elements; and it is not always easy (_e.g._, some alloys)
to say whether a substance is in the one state or the other. This
distinction is well exemplified by the air we breathe. The chemist
finds by analysis that the air is nearly constant in composition,
containing essentially in 100 parts 76.8 by weight of nitrogen
(including about 1 per cent. of the recently-discovered element,
argon), and 23.2 of oxygen. Small proportions of water vapour, carbon
dioxide, etc., may be ignored for our present purposes. In view of this
comparatively uniform composition, the question at first arises as to
whether the air is, or is not, a chemical compound? The answer is in
the negative, for, amongst other things, it can be shown that the ratio
of 76.8 to 23.2 is not that of the atomic weights of the two elements
present, viz., 14 : 16, nor of any simple multiples of these.
We will now quote a few analyses of well-known earths, and explain each
in turn:
_Chemical Composition of China-clays._[8]
-----------+---------+---------------+-------------
| Kaolin. |Kaolin average.|Sandy Kaolin.
+---------+---------------+-------------
Silica | 46.32 | 44.60 | 66.68
Alumina | 39.74 | 44.30 | 26.08
Iron oxide | .27 | .20 | 1.26
Lime | .36 } | 1.60 | .84
Magnesia | .44 } | | trace
Water | 12.67 | 8.74 | 5.14
-----------+---------+---------------+-------------
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