The fundamental difference between the making of optical glass and the
ordinary commercial varieties lies in the individual treatment of each
charge necessary to secure uniformity and regularity, carried even to
the extent of cooling each melting very slowly in its own pot, which
is finally broken up to recover the contents. The tank furnaces are
under heat week in and week out, may hold several hundred tons, and on
this account cannot so readily be held to exactness of composition and
quality.
The optical glass works, too, is provided with a particularly efficient
set of preheating and annealing kilns, for the heat treatment of pots
and glass must be of the most careful and thorough kind.
The production of a melting of optical glass begins with a very gradual
heating of the pot to a bright red heat in one of the kilns. It is
then transferred to its furnace which has been brought to a similar
temperature, sealed in by slabs of firebrick, leaving its mouth easy of
access, and then the heat is pushed up to near the melting temperature
of the mixture in production, which varies over a rather wide range,
from a moderate white heat to the utmost that a regenerative gas
furnace can conveniently produce. After the heating comes the rather
careful process of charging.
The mixture is added a portion at a time, since the fused material
tends to foam, and the raw material as a solid is more bulky than the
fluid. The chemical reactions as the mass fuses are somewhat complex.
In their simplest form they represent the formation of silicates.
At high temperatures the silica acts as a fairly strong acid, and
decomposes the fused carbonates of sodium and potassium with evolution
of gas. This is the _rationale_ of the fluxing action of such alkaline
substances of rather low melting point. Other mixtures act somewhat
analogously but in a fashion commonly too complex to follow.
The final result is a thick solution, and the chief concern of the
optical glass maker is to keep it homogeneous, free from bubbles,
and as nearly colorless as practicable. To the first two ends the
temperature is pushed up to gain fluidity, and frequently substances
are added (e.g., arsenic) which by volatility or chemical effect tend
to form large bubbles from the entrained gases, capable of clearing
themselves from the fluid where fine bubbles would remain. For the same
purpose is the stirring process.
The stirrer is a hard baked cylinder of fire clay fastened to an iron
bar. First heated in the mouth of the pot, the stirrer is plunged in
the molten glass and given a steady rotating motion, the long bar
being swivelled and furnished with a wooden handle for the workman.
This stirring is kept up pretty steadily while the heat is very slowly
reduced until the mass is too thick to manage, the process taking, for
various mixtures and conditions, from three or four hours to the better
part of a day.
[Illustration: FIG. 37.—Testing Optical Glass in the Rough.]
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