Glycerin, the base of Nitro-Glycerin, is produced from most of the
fixed oils and solid fats by the process of saponification, that is, by
treating these fatty bodies with an alkali, or other metallic oxide, in
presence of water, or with water itself at a high temperature. For many
years the Glycerin of commerce was produced from olive oil, by boiling,
in the presence of water, litharge, which yielded the well known lead
plaster or diachylon, and a sweetish liquid, which by evaporation of
the water, was found to be Glycerin; thus procured, however, it was
apt to be contaminated with lead, and therefore very objectionable
for medical purposes. The sources whence it is now procured, are, the
alkaline mother liquor of the soap works, when the soap is separated by
common salt: also the residue of the manufacture of stearic acid for
candles, by heating neutral fats with water or with steam, (Tilghmann’s
process): and the action of muriatic acid on castor oil. It is apt
to be contaminated with sulphuric acid, oxalic acid, lead, and more
generally with uncrystallizable sugars. The demand has vastly increased
of late years for medical purposes, elastic sponge, and retaining
moisture in tobacco, print works, as a preserving agent, and for
floating compasses, etc., etc.
The following are the synonyms of Nitro-Glycerin; Nitrate of Oxide of
Lipyl, (BERZELIUS); Glonoin, Mono-Nitro-Glycerin, Di-Nitro-Glycerin,
Tri-Nitro-Glycerin, (LIECKE)—Symbol, (C₆H₅,) O³, 3NO⁵; (Hydrogen = 1,
Oxygen = 8,) the equivalent or atomic weight is 147.
Pure Nitro-Glycerin is nearly colorless; usually, however, owing to
coloring matter contained in the Glycerin used in its manufacture, it
is of a light yellow-tinted color, oily, without odor, but having an
aromatic taste, Sp. Gr. 1.6 at 60°F, very insoluble in water; mixes
with alcohol (one part to four parts) and ether; it separates from
the alcoholic solution by the addition of water. A vinous taste is
perceptible to the tongue, the maxillary glands are stimulated, and
in a few minutes the individual who has tasted it from a pin’s point
for the first time, is conscious of a persistent, throbbing headache.
Slightly touching, it with the hands produces a like effect; after
a few days of frequent handling, however, the system becomes less
susceptible to these effects, and workmen constantly employed in its
manufacture are not affected by it. It is poisonous, a small quantity
being sufficient to kill a dog, (SOBRERO). It decomposes at 320°F,
giving out red vapors, and explodes at a higher temperature, or by
concussion or percussion, crashing the containing vessel; it ignites by
flame, and burns without explosion, yielding a light ethereal flame of
considerable volume.
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