Pure Nitro-Glycerin may be kept for a year unchanged, (De Vrij). The
writer has exposed it to frost, sun and rain, for three years, and
found it unchanged. Unless perfectly pure, however, it rapidly changes,
becoming of an orange yellow color, evolving fumes, and seems to become
a wholly differing compound, being difficult, when thus changed, to
congeal, except at a much lower temperature than 45°F, and is more
readily exploded.
It very easily decomposes by drying in a warm room with rarefied air,
(WILLIAMSON).
It is instantly decomposed when dissolved in alcohol, by adding an
alcoholic solution of caustic potash, the reaction being so violent as
to eject the mixture from the test tube.
Nitro-Glycerin in contact with the following salts: nitrates of lime,
cobalt, soda, barytes and potash; chlorides of calcium, of barium;
perchloride of iron, carbonate of lime, sulphates of potash, lime and
soda, was found unchanged after a year’s exposure.
INCOMPATIBLES: nitrate of silver precipitates black oxide of silver;
nitrate of copper gives a precipitate of peroxide of copper, the
Nitro-Glycerin remaining, however, bright and apparently unchanged. In
a solution of nitrate of mercury, there appears a white film, a bubble
of protoxide of azote, apparently adherent to the Nitro-Glycerin.
Muriate of ammonia seems to divide the Nitro-Glycerin into two
liquids, a light film supernatant, and the heavier liquid subjacent.
The action of chloride of mercury (calomel) is but very slight.
Protochloride of tin forms a precipitate of peroxide of tin, the
residuary Nitro-Glycerin reflecting light powerfully, and as brightly
as a diamond. Bichromate of potash is partly reduced to chromate.
Sulphate of copper forms a very slight precipitate of oxide of copper,
with apparently no change in the residuary Nitro-Glycerin. Sulphate of
iron decomposes it, giving a voluminous precipitate, with evolution of
nitrous fumes. Sulphuret of ammonia decomposes it, with precipitation
of sulphur. Acetate of lead, chlorine water, ferridcyanide of
potassium, cyanide of potassium, sulphocyanide of potassium, and of
mercury, nitroprusside of sodium decompose it, also the sulphurets of
iron, and potassium.
The action of tin, iron, and lead, slowly decomposing the
Nitro-Glycerin, especially in the presence of an acid, indicates that
metals having an affinity for oxygen, are the most active in promoting
decomposition, evolving at the same time nitrous fumes, or protoxide
of nitrogen, whilst the residuary Nitro-Glycerin does not seem to be
affected; with sulphuretted hydrogen, as with sulphuret of sodium,
potassium and ammonium, the action is prompt, and if these reagents be
added in sufficient quantity, the Nitro-Glycerin is wholly decomposed,
sulphur being precipitated.
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