Chemical substances infiltrate into the cell walls of heart-wood and hence it has a darker color than the sap-wood. Persimmon turns black, walnut purplish brown, sumac yellow, oak light brown, tulip and poplar yellowish, redwood and cedar brownish red. Many woods, as mahogany and oak, darken under exposure, which shows that the substances producing the color are oxidizable and unstable. Wood dyes are obtained by boiling and distilling such woods as sumach, logwood, red sanders, and fustic. Many woods also acquire distinct odors, as camphor, sandalwood, cedar, cypress, pine and mahogany, indicating the presence of oil. As a rule heart-wood is more valuable for timber, being harder, heavier, and drier than sap-wood. In woods like hickory and ash, however, which are used for purposes that require pliability, as in baskets, or elasticity as in handles of rakes and hoes, sap-wood is more valuable than heart-wood. In a transverse section of a conifer, for example Douglas spruce, Fig. 8, the wood is seen to lie in concentric rings, the outer part of the ring being darker in color than the inner part. In reality each of these rings is a section of an irregular hollow cone, each cone enveloping its inner neighbor. Each cone ordinarily constitutes a year's growth, and therefore there is a greater number of them at the base of a tree than higher up. These cones vary greatly in _thickness_, or, looking at a cross-section, the rings vary in _width_; in general, those at the center being thicker than those toward the bark. Variations from year to year may also be noticed, showing that the tree was well nourished one year and poorly nourished another year. Rings, however, do not always indicate a year's growth. "False rings" are sometimes formed by a cessation in the growth due to drouth, fire or other accident, followed by renewed growth the same season. [Illustration: Fig. 8. Section of Douglas Fir, Showing Annual Rings and Knots at Center of Trunk. _American Museum of Natural History, N. Y._] In a radial section of a log, Fig. 8, these "rings" appear as a series of parallel lines and if one could examine a long enough log these lines would converge, as would the cut edges in a nest of cones, if they were cut up thru the center, as in Fig. 9. [Illustration: Fig. 9. Diagram of Radial Section of Log (exaggerated) Showing Annual Cones of Growth.] In a tangential section, the lines appear as broad bands, and since almost no tree grows perfectly straight, these lines are wavy, and give the characteristic pleasing "grain" of wood. Fig. 27, p. 35. The annual rings can sometimes be discerned in the bark as well as in the wood, as in corks, which are made of the outer bark of the cork oak, a product of southern Europe and northern Africa. Fig. 10. [Illustration: Fig. 10. Annual Rings in Bark (cork).]