Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; ElectricityAsimov, Isaac
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Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; Electricity
Asimov, Isaac
Nuclear energy -- Popular works
For instance, he found that a quantity of hydrogen gas invariably
combined with eight times its own mass of oxygen gas to form water. He
guessed that water consisted of combinations of 1 atom of hydrogen with
1 atom of oxygen. (A combination of atoms is called a “molecule” from a
Greek word meaning “a small mass”, and so hydrogen and oxygen atoms can
be said to combine to form a “water molecule”.)
[Illustration: _John Dalton_]
To account for the difference in the masses of the combining gases,
Dalton decided that the oxygen atom was eight times as massive as the
hydrogen atom. If he set the mass of the hydrogen atom at 1 (just for
convenience) then the mass of the oxygen atom ought to be set at 8.
These comparative, or relative, numbers were said to be “atomic
weights”, so that what Dalton was suggesting was that the atomic weight
of hydrogen was 1 and the atomic weight of oxygen was 8. By noting the
quantity of other elements that combined with a fixed mass of oxygen or
of hydrogen, Dalton could work out the atomic weights of these elements
as well.
Dalton’s idea was right, but his details were wrong in some cases. For
instance, on closer examination it turned out that the water molecule
was composed of 1 oxygen atom and 2 hydrogen atoms. For this reason, the
water molecule may be written H₂O, where H is the chemical symbol for a
hydrogen atom, and O for an oxygen atom.
It is still a fact that a quantity of hydrogen combines with eight times
its mass of oxygen, so the single oxygen atom must be eight times as
massive as the 2 hydrogen atoms taken together. The oxygen atom must
therefore be sixteen times as massive as a single hydrogen atom. If the
atomic weight of hydrogen is 1, then the atomic weight of oxygen is 16.
At first it seemed that the atomic weights of the various elements were
whole numbers and that hydrogen was the lightest one. It made particular
sense, then, to consider the atomic weight of hydrogen as 1, because
that made all the other atomic weights as small as possible and
therefore easy to handle.
The Swedish chemist Jöns Jakob Berzelius (1779-1848) continued Dalton’s
work and found that elements did not combine in quite such simple
ratios. A given quantity of hydrogen actually combined with a little bit
less than eight times its mass of oxygen. Therefore if the atomic weight
of hydrogen were considered to be 1, the atomic weight of oxygen would
have to be not 16, but 15.87.
[Illustration: _Jöns Jakob Berzelius_]
Public-domain text, read in full here on John Shaqi.
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