Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; ElectricityAsimov, Isaac
Science
Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; Electricity
Asimov, Isaac
Nuclear energy -- Popular works
As it happens, oxygen combines with more elements (and more easily) than
hydrogen does. The ratio of its atomic weight to that of other elements
is also more often a whole number. In working out the atomic weight of
elements it was therefore more convenient to set the atomic weight of
oxygen at a whole number than that of hydrogen. Berzelius did this, for
instance, in the table of atomic weights he published in 1828. At first
he called the atomic weight of oxygen 100. Then he decided to make the
atomic weights as small as possible, without allowing any atomic weight
to be less than 1. For that reason, he set the atomic weight of oxygen
at exactly 16 and in that case, the atomic weight of hydrogen had to be
placed just a trifle higher than 1. The atomic weight of hydrogen became
1.008. This system was retained for nearly a century and a half.
Throughout the 19th century, chemists kept on working out atomic weights
more and more carefully. By the start of the 20th century, most elements
had their atomic weights worked out to two decimal places, sometimes
three.
A number of elements had atomic weights that were nearly whole numbers
on the “oxygen = 16” standard. The atomic weight of aluminum was just
about 27, that of calcium almost 40, that of carbon almost 12, that of
gold almost 197, and so on.
On the other hand, some elements had atomic weights that were far
removed from whole numbers. The atomic weight of chlorine was close to
35.5, that of copper to 63.5, that of iron to 55.8, that of silver to
107.9, and so on.
Throughout the 19th century, chemists did not know why so many atomic
weights were whole numbers, while others weren’t. They simply made their
measurements and recorded what they found. For an explanation, they had
to wait for a line of investigation into electricity to come to
fruition.
ELECTRICITY
Units of Electricity
Through the 18th century, scientists had been fascinated by the
properties of electricity. Electricity seemed, at the time, to be a very
fine fluid that could extend through ordinary matter without taking up
any room.
Electricity did more than radiate through matter, however. It also
produced important changes in matter. In the first years of the 19th
century, it was found that a current of electricity could cause
different atoms or different groups of atoms to move in opposite
directions through a liquid in which they were dissolved.
The English scientist Michael Faraday (1791-1867) noted in 1832 that a
given quantity of electricity seemed to liberate the same number of
atoms of a variety of different elements. In some cases, though, it
liberated just half the expected number of atoms; or even, in a few
cases, just a third.
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