Letters of a Radio-Engineer to His Son — John Stuart Mill — John Shaqi
Letters of a Radio-Engineer to His Son
John Stuart Mill · en
I remember when I mixed the sulphuric acid with water that I learned to
pour the acid into the water and not the other way around. Spatterings
of sulphuric acid are not good for hands or clothes. With this solution
I filled the jar almost to the top and then hung over the edge a sort of
a crow's foot shape of cast zinc. The zinc reached down into the
sulphuric acid solution. There was a binding post on it to which a wire
could be connected. This wire and the one which came from the plate of
copper at the bottom were the two terminals of the battery. We called
the wire from the copper "positive" and the one from the zinc
"negative."
Now we shall see why and how the battery worked. The molecules of
sulphuric acid dissociate in solution just as do those of copper
sulphate. When sulphuric acid molecules split, the sulphate part goes
away with two electrons which don't belong to it and each of the
hydrogen atoms goes away by itself but without its electron. We call
each a "hydrogen ion" but you can see that each is a single proton.
In the two solutions are pieces of zinc and copper. Zinc is like all the
rest of the metals in one way. Atoms of metals always have lonely
electrons for which there doesn't seem to be room in the game which is
going on around their nuclei. Copper as we saw has two lonely electrons
in each atom. Zinc also has two. Some metals have one and some two and
some even more lonely electrons in each atom.
What happens then is this. The sulphate ions wandering around in the
weak solution of sulphuric acid come along beside the zinc plate and
beckon to its atoms. The sulphate ions had a great deal rather play the
game called "zinc sulphate" than the game called "hydrogen sulphate." So
the zinc atoms leave their places to join with the sulphate ions. But
wait a minute! The sulphate ions have two extra electrons which they
kept from the hydrogen atoms. They don't need the two lonely electrons
which each zinc atom could bring and so the zinc atom leaves behind it
these unnecessary electrons.
Every time a zinc atom leaves the plate it fails to take all its
electrons with it. What leaves the zinc plate, therefore, to go into
solution is really not a zinc atom but is a zinc ion; that is, it is the
nucleus of a zinc atom and all except two of the planetary electrons.
Every time a zinc ion leaves the plate there are left behind two
electrons. The plate doesn't want them for all the rest of its atoms
have just the same number of protons as of electrons. Where are they to
go? We shall see in a minute.
Sometimes the zinc ions which have got into solution meet with sulphate
ions and form zinc sulphate molecules. But if they do these molecules
split up sooner or later into ions again. In the upper part of the
liquid in the jar, therefore, there are sulphate ions which are negative
and two kinds of positive ions, namely, the hydrogen ions and the zinc
ions.