The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
Again, in the original work on mercury droplets which I produced both
by atomizing liquid mercury and by condensing the vapor from boiling
mercury,[121] I noticed that such droplets evaporated for a time even
more rapidly than oil, and other observers who have since worked with
mercury have reported the same behavior.[122] The amount of this effect
may be judged from the fact that one particular droplet of mercury
recently under observation in this laboratory had at first a speed
of 1 cm. in 20 seconds, which changed in half an hour to 1 cm. in 56
seconds. The slow cessation, however, of this evaporation indicates
that the drop slowly becomes coated with some sort of protecting
film. Now, if any evaporation whatever is going on while successive
times of fall are being observed—and as a matter of fact changes
due to evaporation or condensation are always taking place to some
extent—the apparent will be larger than
that due to Brownian movements, even though these movements are large
[Pg 172]
enough to prevent the observer from noticing, in taking twenty or
thirty readings, that the drop is continually changing. These changes
combined with the fluctuations in due to the observer’s error are
sufficient, I think, to explain all of the low values of e obtained by
Dr. Ehrenhaft by the Brownian-movement method. Indeed, I have myself
repeatedly found coming out less than half of its proper value
until I corrected for the evaporation of the drop, and this was
true when the evaporation was so slow that its rate of fall changed but
1 or 2 per cent in a half-hour. But it is not merely evaporation which
introduces an error of this sort. The running down of the batteries,
the drifting of the drop out of focus, or anything which causes changes
in the times of passage across the equally spaced cross-hairs tends to
decrease the apparent value of . There is, then, so far as I
can see, no evidence at all in any of the data published to date that
the Brownian-movement method actually does yield too low a value of
“”, and very much positive evidence that it does not was given in
the preceding chapter.
Indeed, the same type of Brownian-movement work which Fletcher and I
did upon oil-drops ten years ago (see preceding chapter) has recently
been done in Vienna with the use of particles of selenium, and with
results which are in complete harmony with our own. The observer,
E. Schmid,[123] takes as many as 1,500 “times of fall” upon a given
particle, the radius of which is in one case as low as
—quite as minute as any used by Dr. Ehrenhaft—and
obtains in all cases values of by “the Brownian-movement method”
[Pg 173]
which are in as good agreement with our own as could be expected in
view of the necessary observational error. This complete check of our
work in Vienna itself should close the argument so far as the Brownian
movements are concerned.