The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
These sharp deflections, which occasionally amount to as much as 150°
to 180°, lend the strongest of support to the view that the atom
consists of a heavy positively charged nucleus about which are grouped
enough electrons to render the whole atom neutral. But the fact that in
these experiments the -particle goes through 130,000 atoms
without approaching near enough to this central nucleus to suffer
appreciable deflection more than two or three times constitutes the
most convincing evidence that this central nucleus which holds the
negative electrons within the atomic system occupies an excessively
minute volume, just as we computed from the electromagnetic theory
of the origin of mass that the positive electron ought to do.
Indeed, knowing as he did by direct measurement the speed of the
-particle, Rutherford, who is largely responsible for the
nucleus-atom theory, first computed,[140] with the aid of the inverse
square law, which we know to hold between charged bodies of dimensions
which are small compared with their distances apart, how close the
-particle would approach to the nucleus of a given atom
like that of gold before it would be turned back upon its course (see
Appendix F). The result was in the case of gold, one of the heaviest
atoms, about , and in the case of hydrogen, the
lightest atom, about . These are merely upper
limits for the dimensions of the nuclei.
However uncertain, then, we may feel about the sizes of positive and
negative electrons computed from the electromagnetic theory of the
origin of the mass, we may regard it as fairly well established by
such direct experiments as these that the electronic constituents of
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atoms are as small, in comparison with the dimensions of the atomic
systems, as are the sun and planets in comparison with the dimensions
of the solar system. Indeed, when we reflect that we can shoot helium
atoms by the billion through a thin-walled highly evacuated glass
tube without leaving any holes behind, i.e., without impairing in the
slightest degree the vacuum or perceptibly weakening the glass, we see
from this alone that the atom itself must consist mostly of “hole”; in
other words, that an atom, like a solar system, must be an exceedingly
loose structure whose impenetrable portions must be extraordinarily
minute in comparison with the penetrable portions. The notion that an
atom can appropriate to itself all the space within its boundaries
to the exclusion of all others is then altogether exploded by these
experiments. A particular atom can certainly occupy the same space at
the same time as any other atom if it is only endowed with sufficient
kinetic energy. Such energies as correspond to the motions of thermal
agitation of molecules are not, however, sufficient to enable one
atom to penetrate the boundaries of another, hence the seeming
impenetrability of atoms in ordinary experiments in mechanics. That
there is, however, a portion of the atom which is wholly impenetrable