The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
to the alpha particles is definitely proved by experiments of the
sort we have been considering; for it occasionally happens that an
alpha particle hits this nucleus “head on,” and, when it does so, it
is turned straight back upon its course. As indicated above, the size
of this impenetrable portion, which may be defined as the size of the
nucleus, is in no case larger than ¹⁄₁₀₀₀₀ the diameter of the atom,
and yet there may be contained within it, as will presently be
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shown, several hundred positive and negative electrons, so that the
excessive minuteness of these bodies is established, altogether without
reference to any theory as to what they are.
IV. THE NUMBER OF ELECTRONS IN AN ATOM
If it be considered as fairly conclusively established by the
experiments just described that an atom consists of a heavy but very
minute positively charged nucleus which holds light negative electrons
in some sort of a configuration about it, then the number of negative
electrons outside the nucleus must be such as to have a total charge
equal to the free positive charge of the nucleus, since otherwise the
atom could not be neutral.
But the positive charge on the nucleus has been approximately
determined as follows: With the aid of the knowledge, already obtained
through the determination of , of the exact number of atoms in a
given weight of a given substance, Sir Ernest Rutherford[141] first
computed the chance that a single helium atom in being shot with a
known speed through a sheet of gold foil containing a known number of
atoms per unit of area of the sheet would suffer a deflection through a
given angle. This computation can easily be made in terms of the known
kinetic energy and charge of the -particle, the known number
of atoms in the gold foil, and the unknown charge on the nucleus of
the gold atom (see Appendix F). Geiger and Marsden[142] then actually
counted in Rutherford’s laboratory, by means of the scintillations
produced on a zinc-sulphide screen, what fraction of, say, a thousand
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-particles, which were shot normally into the gold foil, were
deflected through a given angle, and from this observed number and
Rutherford’s theory they obtained the number of free positive charges
on the nucleus of the gold atom.