The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
When, now, the hydrogen nucleus is replaced by that of helium, which
is four times as heavy, the common center of gravity is still closer
to the nucleus, so that the helium-nucleus describes a much smaller
circle than did that of hydrogen. This situation is responsible for
a slight but accurately predictable difference in the energies of
the two orbits, which should cause the spectral lines produced by
electron-jumps to these two different orbits to be slightly displaced
from one another.
This predicted slight displacement between the hydrogen and helium
lines is not only found experimentally, but the most refined and exact
of recent measurements has shown that the observed displacement
agrees with the predicted value to within a small fraction of 1 per
cent.
This not only constitutes excellent evidence for the orbit theory, but
it seems to be irreconcilable with a ring-electron theory once favored
by some authors, since it requires the mass of the electron to be
concentrated at a point.
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The next amazing success of the orbit theory came when Sommerfeld[159]
showed that the “quantum” principle underlying the Bohr theory ought
to demand two different hydrogen orbits corresponding to the second
quantum state—second orbit from the nucleus—one a circle and one
an ellipse. And by applying the relativity theory to the change in
mass of the electron with its change in speed as it moves through the
different portions (perihelion and aphelion) of its orbit, he showed
that the circular and elliptical orbits should have slightly different
energies, and consequently that both the hydrogen and the helium lines
corresponding to the second quantum state should be close doublets.
Now not only is this found to be the fact, but the measured
separation of these two doublet lines agrees precisely with the
predicted value, so that this again constitutes extraordinary
evidence for the validity of the orbit-conceptions underlying the
computation.
In Fig. 27 the two orbits which are here in question are those which
are labeled and ; the large numeral denoting the total
quantum number, and the subscript the auxiliary, or azimuthal,
quantum number which determines the ellipticity of the orbit. The
figure is introduced to show the types of stationary orbits which the
extended Bohr theory permits. For total quantum number 1 there is but
one possible orbit, a circle. For total quantum numbers 2, 3, 4, etc.,
there are 2, 3, 4, etc., possible orbits, respectively. The ratio of
the auxiliary to the total quantum number gives the ratio of the minor
and major axes of the ellipse. The fourth quantum state, for example,
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has four orbits, , , , , all of which have the
same major axis, but minor axes which increase in the ratios 1, 2, 3,
4 up to equality, in the circle (), with the major axis. It is
this multiplicity of orbits which predicts with beautiful accuracy the
“fine-structure” of all of the lines due to atomic hydrogen and to
helium.