The electron, its isolation and measurement and the determination of some of its properties — John Stuart Mill — John Shaqi
The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
Fig. 27—Bohr-Sommerfeld model of the hydrogen atom
with stationary orbits corresponding to principal quantum numbers and
auxiliary or azimuthal quantum numbers.
The next quantitative success of the Bohr theory came when
Epstein,[160] of the California Institute, applied his amazing grasp
of orbit theory to the exceedingly difficult problem of computing
the perturbations in electron orbits, and hence the change in energy
of each, due to exciting hydrogen and helium atoms to radiate in an
electrostatic field. He thus predicted the whole complex character
of what we call the “Stark effect,” showing just how many new lines
[Pg 220]
were to be expected and where each one should fall, and then the
spectroscope yielded, in practically every detail, precisely the result
which the Epstein theory demanded.
Another quantitative success of the orbit theory is one which Mr. I.
S. Bowen and the author,[161] at the California Institute, have just
brought to light. Through creating what we call “hot sparks” in extreme
vacuum we have succeeded in stripping in succession, 1, 2, 3, 4, 5, and
6 of the valence, or outer, electrons from the atoms studied. In going
from lithium, through beryllium, boron and carbon to nitrogen, we have
thus been able to work with stripped atoms of all these substances.
Now these stripped atoms constitute structures which are all exactly
alike save that the fields in which the single electron is radiating as
it returns toward the nucleus increase in the ratios 1, 2, 3, 4, 5, as
we go from stripped lithium to stripped nitrogen. We have applied
the relativity-doublet formula, which, as indicated above, Sommerfeld
had developed for the simple nucleus-electron system found in hydrogen
and ionized helium, and have found that it not only predicts everywhere
the observed doublet-separation of the doublet-lines produced by all
these stripped atoms, but that it enables us to compute how many
electrons are in the inmost, or shell, screening the nucleus from
the radiating electron. This number comes out just 2, as we know from
radioactive and other data that it should. (See inset photograph,
Fig. 37, following Fig. 36, opposite p. 260.)
Further, when we examine the spectra due to the stripped atoms of the
group of elements from sodium to sulphur, one electron having been
[Pg 221]
knocked off from sodium, two from magnesium, three from aluminum, four
from silicon, five from phosphorus, and six from sulphur, we ought to
find that the number of screening electrons in the two inmost shells
combined is , and it does come out 10, precisely as
predicted, and all this through the simple application of the
principle of change of mass with speed in elliptical electronic orbits
of the type shown in Fig. 27.