The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
Thus, the total luminous energy falling per second from a standard
candle on a square centimeter at a distance of 3 m. is 1 erg.[182]
Hence the amount falling per second on a body of the size of an atom,
i.e., of cross-section , is , but
the energy with which an electron is ejected by light of
wave-length (millionths millimeter) is ,
or four thousand times as much. Since not a third of
the incident energy is in wave-lengths shorter than ,
a surface of sodium or lithium which is sensitive up to
[Pg 252]
should require, even if all tills energy were in one wave-length,
which it is not, at least 12,000 seconds or 4 hours of illumination
by a candle 3 m. away before any of its atoms could have received,
all told, enough energy to discharge an electron. Yet the electron is
observed to shoot out the instant the light is turned on. It is true
that Lord Rayleigh has shown[183] that an atom may conceivably absorb
wave-energy from a region of the order of magnitude of the square of
a wave-length of the incident light rather than of the order of its
own cross-section. This in no way weakens, however, the cogency of the
type of argument just presented, for it is only necessary to apply the
same sort of analysis to the case of -rays, the wave-length
of which is sometimes as low as a hundredth of an atomic diameter
( cm.), and the difficulty is found still more pronounced.
Thus Rutherford[184] estimates that the total -ray energy
radiated per second by one gram of radium cannot possibly be more
than . Hence at a distance of 100 meters,
where the -rays from a gram of radium would be easily
detectable, the total -ray energy falling per second on a
square millimeter of surface, the area of which is ten-thousand
billion times greater than that of an atom, would be
.
This is very close to the energy with which -rays are actually
observed to be ejected by these -rays, the velocity of
ejection being about nine-tenths that of light. Although, then, it
should take ten thousand billion seconds for the atom to gather in
this much energy from the -rays, on the basis of classical
[Pg 253]
theory, the -ray is observed to be ejected with this energy
as soon as the radium is put in place. This shows that if we are going
to abandon the Thomson-Einstein hypothesis of localized energy, which
is of course competent to satisfy these energy relations, there is no
alternative but to assume that at some previous time the electron had
absorbed and stored up from light of this wave-length enough energy
so that it needed but a minute addition at the time of the experiment
to be able to be ejected from the atom with the energy .
What sort of an absorbing and energy-storing mechanism an atom might
have which would give it the weird property of storing up energy to
the value , where is the frequency of the incident
light, and then shooting it all out at once, is terribly difficult to
conceive. Or, if the absorption is thought of as due to resonance it