The electron, its isolation and measurement and the determination of some of its properties — John Stuart Mill — John Shaqi
The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
Thomson and his pupils found that the conductivity induced in gases
by X-rays disappeared when the gas was sucked through glass wool.[11]
It was also found to be reduced when the air was drawn through narrow
metal tubes. Furthermore, it was removed entirely by passing the
stream of conducting gas between plates which were maintained at a
sufficiently large potential difference. The first two experiments
showed that the conductivity was due to something which could be
removed from the gas by filtration, or by diffusion to the walls of
a metal tube; the last proved that this something was electrically
charged.
When it was found, further, that the electric current obtained from air
existing between two plates and traversed by X-rays rose to a maximum
as the P.D. between the plates increased, and then reached a value
which was thereafter independent of this potential difference; and,
further, that this conductivity of the air died out slowly through
a period of several seconds when the X-ray no longer acted, it was
evident that the qualitative proof was complete that gas conduction
must be due to charged particles produced in the air at a definite
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rate by a constant source of X-rays, and that these charged particles,
evidently of both plus and minus signs, disappear by recombination when
the rays are removed. The maximum or saturation currents which
could be obtained when a given source was ionizing the air between two
plates whose potential difference could be varied were obviously due to
the fact that when the electric field between the plates became strong
enough to sweep all the ions to the plates as fast as they were formed,
none of them being lost by diffusion or recombination, the current
obtained could, of course, not be increased by further increase in the
field strength. Thus gas conduction was definitely shown about 1896 to
be electrolytic in nature.
IV. COMPARISON OF THE GASEOUS ION AND THE
ELECTROLYTIC ION
But what sort of ions were these that were thus formed? We did
not know the absolute value of the charge on a univalent ion in
electrolysis, but we did know accurately . Could this be found
for the ions taking part in gas conduction? That this question was
answered affirmatively was due to the extraordinary insight and
resourcefulness of J. J. Thomson and his pupils at the Cavendish
Laboratory in Cambridge, both in working out new theoretical relations
and in devising new methods for attacking the new problems of gaseous
conduction. These workers found first a method of expressing the
quantity in terms of two measurable constants, called (1) the
mobility of gaseous ions and (2) the coefficient of diffusion of these
ions. Secondly, they devised new methods of measuring these two
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constants—constants which had never before been determined. The theory
of the relation between these constants and the quantity will be
found in Appendix A. The result is