The electron, its isolation and measurement and the determination of some of its properties — John Stuart Mill — John Shaqi
The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
It has been since shown by a number of observers that the ratio of the
mobilities of the positive and negative ions is not at all the same
in other gases as it is in air. In carbon dioxide the two mobilities
have very nearly the same value, while in chlorine, water vapor,
and the vapor of alcohol the positive ion apparently has a slightly
larger mobility than the negative. There seems to be some evidence
that the negative ion has the larger mobility in gases which are
electro-positive, while the positive has the larger mobility in the
gases which are strongly electro-negative. This dependence of the ratio
of mobilities upon the electro-positive or electro-negative character
of the gas has usually been considered strong evidence in favor of the
cluster-ion theory.
Very recently, however, Loeb,[17] who has worked at the Ryerson
Laboratory on mobilities in powerful electric fields, and Wellish,[18]
who, at Yale, has measured mobilities at very low pressures, have
concluded that their results are not consistent with the cluster-ion
theory, but must rather be interpreted in terms of the so-called
Atom-ion Theory. This theory seeks to explain the relative sluggishness
of ions, as compared with molecules, by the additional resistance
which the gaseous medium offers to the motion of a molecule through
it when that molecule is electrically charged. According to
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this hypothesis, the ion would be simply an electrically charged
molecule.
So far as the negative ion is concerned, the situation at the moment
seems to be in favor of the atom-ion theory. There has recently
developed strong evidence[19] that although in some very pure gases,
such as helium, argon, and even nitrogen, the negative electron cannot
find attachment at all, when it does attach so as to form ions of the
mobility mentioned above, it carries with it thereafter but a single
molecule.
On the other hand, Erikson[20] and Wahlin[21] have apparently shown
quite conclusively that if the mobility of the positive ion in air is
measured within .03 second of the time of its formation, its value is
identical with that of the negative, namely, 1.8 cm. per second, while
a short time thereafter it has sunk to about 1.4 cm. per second because
of the addition of one more molecule, thus forming a very stable
two-molecule-ion group.
Fortunately, the quantitative evidence for the electrolytic nature of
gas conduction is in no way dependent upon the correctness of either
one of the theories as to the nature of the ion. It depends simply
upon the comparison of the values of obtained from electrolytic
measurements, and those obtained from the substitution in equation (3)
of the measured values of and for gaseous ions.