The electron, its isolation and measurement and the determination of some of its properties — John Stuart Mill — John Shaqi
The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
It had been known, even to Laplace and Lavoisier a hundred years
before, that the hydrogen gas evolved when a metal dissolves in an
acid carries with it an electrical charge. This “natural method” of
obtaining a charge on a gas was scarcely studied at all, however, until
after the impulse to the study of the electrical properties of gases
had been given by the discovery in 1896 that electrical properties can
be artificially imparted to gases by X-rays. Townsend’s paper appeared
within a year of that time. Enright[30] had indeed found that the
hydrogen given off when iron is dissolving in sulphuric acid carries
with it a positive charge, but Oliver Lodge[31] had urged that it was
not the gas itself which carries the charge but merely the spray, for
the frictional electrification of spray was a well-known phenomenon.
Indeed, it has always been assumed that the gas molecules which rise
from the electrodes in electrolysis are themselves neutral. Townsend,
however, first showed that some of these molecules are charged,
although there are indeed a million million neutral ones for every one
carrying a charge. He found that both the oxygen and the hydrogen which
appear at the opposite electrodes when sulphuric acid is electrolyzed
are positively charged, while when the electrolyte is caustic potash
both the oxygen and the hydrogen given off are negative. Townsend’s
electrolyzing currents were from 12 to 14 amperes. He got in this way
many more ions per cubic centimeter than he could produce with X-rays,
the total charge per cubic centimeter being as large as
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When these charged gases were bubbled through water they formed a
cloud. This cloud could be completely removed by bubbling through
concentrated sulphuric acid or any drying agent, but when the gas came
out again into the atmosphere of the room it again condensed moisture
and formed a stable cloud. Townsend says that “the process of forming
the cloud in positive or negative oxygen by bubbling through water,
and removing it again by bubbling through sulphuric acid, can be gone
through without losing more than 20 or 25 per cent of the original
charge on the gas.” This means simply that the ions condense the
water about them when there is an abundance of moisture in the air,
but when the cloud is carried into a perfectly dry atmosphere, such
as that existing in a bubble surrounded on all sides by concentrated
sulphuric acid, the droplets of water evaporate and leave the charge
on a molecule of air as it was at first. The 20 or 25 per cent loss of
charge represents the fraction of the droplets with their charges which
actually got into contact with and remained in the liquids through
which the gas was being bubbled.
In order to find the charge on each ion, Townsend took the following
five steps:
1. He assumed that in saturated water vapor each ion condensed moisture
about it, so that the number of ions was the same as the number of
droplets.