The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
From these two equations was eliminated and obtained
in terms of . Introducing Perrin’s value of , De Broglie
obtained from one series of measurements ;
from another series on larger particles he got a mean value several
times larger—a result which he interpreted as indicating multiple
charges on the larger particles. Although these results represent
merely mean values for many drops which are not necessarily all alike,
either in radius or charge, yet they may be considered as the first
experimental evidence that Einstein’s equation holds approximately,
in gases, and they are the more significant because nothing has to
be assumed about the size of the particles, if they are all alike in
charge and radius, or about the validity of Stokes’s Law in gases, the
-factor being eliminated.
[Pg 150]
The development of the oil-drop method made it possible to subject the
Brownian-movement theory to a more accurate and convincing experimental
test than had heretofore been attainable, and that for the following
reasons:
1. It made it possible to hold, with the aid of the vertical electrical
field, one particular particle under observation for hours at a time
and to measure as many displacements as desired on it alone instead of
assuming the identity of a great number of particles, as had been done
in the case of suspensions in liquids and in De Broglie’s experiments
in gases.
2. Liquids are very much less suited than are gases to convincing
tests of any kinetic hypothesis, for the reason that prior to
Brownian-movement work we had no satisfactory kinetic theory of liquids
at all.
3. The absolute amounts of the displacements of a given particle in air
are 8 times greater and in hydrogen 15 times greater than in water.
4. By reducing the pressure to low values the displacements can easily
be made from 50 to 200 times greater in gases than in liquids.
5. The measurements can be made independently of the most troublesome
and uncertain factor involved in Brownian-movement work in liquids,
namely, the factor , which contains the radius of the particle and
the law governing its motion through the liquid.
Accordingly, there was begun in the Ryerson Laboratory, in 1910, a
series of very careful experiments in Brownian movements in gases.
Svedberg,[83] in reviewing this subject in 1913, considers this
“the only exact investigation of quantitative Brownian movements in
gases.” A brief summary of the method and results was published by the
author.[84] A full account was published by Mr. Harvey Fletcher in
[Pg 151]
May, 1911,[85] and further work on the variation of Brownian movements
with pressure was presented by the author the year following.[86] The
essential contribution of this work as regards method consisted in the
two following particulars:
1. By combining the characteristic and fully tested equation of the
oil-drop method, namely,
with the Einstein Brownian-movement equation, namely,