The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
it was possible to obtain the product without any reference
to the size of the particle or the resistance of the medium to its
motion. This quantity could then be compared with the same product
obtained with great precision from electrolysis. The experimental
procedure consists in balancing a given droplet and measuring, as in
any Brownian-movement work, the quantity ,
then unbalancing it and measuring , and
(; the combination of (24) and (25) then gives
Since it is awkward to square each displacement before
averaging, it is preferable to modify by substituting from the Maxwell
distribution law, which holds for Brownian displacements as well as
[Pg 152]
for molecular velocities, the relation
We obtain thus
or
The possibility of thus eliminating the size of the particle and with
it the resistance of the medium to its motion can be seen at once from
the simple consideration that so long as we are dealing with one
and the same particle the ratio between the force acting
and the velocity produced by it must be the same, whether the acting
force is due to gravity or an electrical held, as in the oil-drop
experiments, or to molecular impacts as in Brownian-movement work. De
Broglie might have made such an elimination and calculation of
in his work, had his Brownian displacements and mobilities in electric
fields been made on one and the same particle, but when the two sets of
measurements are made on different particles, such elimination would
involve the very uncertain assumption of identity of the particles
in both charge and size. Although De Broglie did actually make this
assumption, he did not treat his data in the manner indicated, and the
first publication of this method of measuring as well as the
first actual determination was made in the papers mentioned above.
[Pg 153]
Some time later E. Weiss reported similar work to the Vienna
Academy.[87]
2. Although it is possible to make the test of in just the
method described and although it was so made in the case of one or
two drops, Mr. Fletcher worked out a more convenient method, which
involves expressing the displacements in terms of the
fluctuations in the time required by the particle to fall a given
distance and thus dispenses with the necessity of balancing the drop at
all. I shall present another derivation which is very simple and yet of
unquestionable validity.