The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
In equation (28) let be the time required by the particle, if
there were no Brownian movements, to fall between a series of equally
spaced cross-hairs whose distance apart is . In view of such
movements the particle will have moved up or down a distance
in the time . Let us suppose this distance to be up. Then
the actual time of fall will be , in which
is now the time it takes the particle to fall the distance .
If now is small in comparison with , that is,
if is small in comparison with (say ⅒ or less), then
we shall introduce a negligible error (of the order ¹⁄₁₀₀ at the most)
if we assume that in which is
the mean velocity under gravity. Replacing then in (28)
(, by in
which is the square of the average
difference between an observed time of fall and the mean time of fall
[Pg 154]
, that is, the square of the average fluctuation in the time
of fall through the distance , we obtain after replacing the ideal
time by the mean time
In any actual work will be kept considerably
less than ⅒ the mean time if the irregularities due to
the observer’s errors are not to mask the irregularities due to the
Brownian movements, so that (29) is sufficient for practically all
working conditions.[88]
The work of Mr. Fletcher and of the author was done by both of the
methods represented in equations (28) and (29). The 9 drops reported
upon in Mr. Fletcher’s paper in 1911[89] yielded the results shown
below in which is the number of displacements used in each case
in determining or .
TABLE XIV
1.68
125
1.67
136
1.645
321
1.695
202
1.73
171
1.65
200
1.66
84
1.785
411
1.65
85
When weights are assigned proportional to the number of observations
taken, as shown in the last column of Table XIV, there results
[Pg 155]
for the weighted mean value which represents an average of 1,735
displacements,
or , as against ,
the value found in electrolysis. The agreement between theory
and experiment is then in this case about as good as one-half of 1 per
cent, which is well within the limits of observational error.
This work seemed to demonstrate, with considerably greater precision
than had been attained in earlier Brownian-movement work and with a
minimum of assumptions, the correctness of the Einstein equation, which
is in essence merely the assumption that a particle in a gas, no matter
how big or how little it is or out of what it is made, is moving about
with a mean translatory kinetic energy which is a universal constant
dependent only on temperature. To show how well this conclusion has
been established I shall refer briefly to a few later researches.