A History of Science — Volume 4Williams, Henry Smith
History
A History of Science — Volume 4
Williams, Henry Smith
Science -- History
"As early as 1800," writes Davy, "I had found that when separate
portions of distilled water, filling two glass tubes, connected by moist
bladders, or any moist animal or vegetable substances, were submitted
to the electrical action of the pile of Volta by means of gold wires,
a nitro-muriatic solution of gold appeared in the tube containing the
positive wire, or the wire transmitting the electricity, and a solution
of soda in the opposite tube; but I soon ascertained that the muriatic
acid owed its existence to the animal or vegetable matters employed;
for when the same fibres of cotton were made use of in successive
experiments, and washed after every process in a weak solution of nitric
acid, the water in the apparatus containing them, though acted on for
a great length of time with a very strong power, at last produced no
effects upon nitrate of silver.
"In cases when I had procured much soda, the glass at its point of
contact with the wire seemed considerably corroded; and I was confirmed
in my idea of referring the production of the alkali principally to
this source, by finding that no fixed saline matter could be obtained
by electrifying distilled water in a single agate cup from two points of
platina with the Voltaic battery.
"Mr. Sylvester, however, in a paper published in Mr. Nicholson's journal
for last August, states that though no fixed alkali or muriatic acid
appears when a single vessel is employed, yet that they are both formed
when two vessels are used. And to do away with all objections with
regard to vegetable substances or glass, he conducted his process in
a vessel made of baked tobacco-pipe clay inserted in a crucible of
platina. I have no doubt of the correctness of his results; but the
conclusion appears objectionable. He conceives, that he obtained fixed
alkali, because the fluid after being heated and evaporated left a
matter that tinged turmeric brown, which would have happened had it
been lime, a substance that exists in considerable quantities in all
pipe-clay; and even allowing the presence of fixed alkali, the materials
employed for the manufacture of tobacco-pipes are not at all such as to
exclude the combinations of this substance.
Public-domain text, read in full here on John Shaqi.
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