A History of Science — Volume 5Williams, Henry Smith
History
A History of Science — Volume 5
Williams, Henry Smith
Science -- History
conduction at low temperatures are quite beyond the reach of present
explanation. They must await a fuller knowledge of molecular conditions
in general than is at present available--a knowledge to which the
low-temperature work itself seems one of the surest channels.
Even further beyond the reach of present explanation are the facts as to
magnetic conditions at low temperatures. Even as to the facts themselves
different experimenters have differed somewhat, but the final conclusion
of Professor Dewar is that, after a period of fluctuation, the power of
a magnet repeatedly subjected to a liquid-air bath becomes permanently
increased. Various substances not markedly magnetic at ordinary
temperatures become so when cooled. Among these, as Professor Dewar
discovered, is liquid oxygen itself. Thus if a portion of liquid air be
further cooled until it assumes a semi-solid condition, the oxygen may
be drawn from the mass by a magnet, leaving a pure nitrogen jelly. These
facts are curious enough, and full of suggestion, but like all other
questions having to do with magnetism, they hold for the present
generation the double fascination of insoluble mystery. To be sure, one
may readily enough suggest that if magnetism be really a whirl in the
ether, this whirl is apparently interfered with by the waves of radiant
heat; or, again, that magnetism is presumably due to molecular motions
which are apparently interfered with by another kind of molecular
motions which we call heat vibrations; but there is a vagueness about
the terms of such guesses that leaves them clearly within the category
of explanations that do not explain.
When it comes to the phenomena of light, we can, as is fitting, see
our way a little more clearly, since, thanks to Thomas Young and his
successors, we know pretty definitely what light really is. So when
we learn that many substances change their color utterly at low
temperatures--red things becoming yellow and yellow things white,
for example--we can step easily and surely to at least a partial
explanation. We know that the color of any object depends simply
upon the particular ether waves of the spectrum which that particular
substance absorbs; and it does not seem anomalous that molecules packed
close together at--180° of temperature should treat the ether waves
differently than when relatively wide apart at an ordinary temperature.
Yet, after all, that may not be the clew to the explanation. The packing
of the molecules may have nothing to do with it. The real explanation
may lie in the change of the ether waves sent out by the vibrating
molecule; indeed, the fact that the waves of radiant heat and those of
light differ only in amplitude lends color to this latter supposition.
So the explanation of the changed color of the cooled substance is at
best a dubious one.
Public-domain text, read in full here on John Shaqi.
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