A new system of chemical philosophy, Volume 2, Part 1 — John Shaqi
A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
except in a small degree so as to give the yellow colour. In this state
it has been considered as a neutral muriate. By a moderately bright red
heat this powder is decomposed and leaves a black spongy mass which is
found to be pure platina.
The insoluble muriate of platina according to Mr. E. Davy, contains
72.5 per cent. of platina, and Berzelius finds 73.3; the loss is
considered as oxymuriatic acid; hence from the known proportions of
this acid Berzelius infers the constituents of 100 muriate = 73.3
platina, 6.075 oxygen and 20.625 muriatic acid; or 100 platina take
8.3 oxygen. The near agreement of the above authors is favourable to
the accuracy of their results; but I have found some difficulty in
obtaining the insoluble muriate free from the soluble one, and at the
same time from reduced platina because the precise degree of heat
requisite to produce it is neither well known nor easily attained; and
it is desirable that a certain weight of platina should be dissolved
and the same weight reproduced as a confirmation of accuracy. From a
train of experiments on the soluble and insoluble muriates of platina,
the salts being obtained from the purified laminated metal, I am
disposed to consider the above results as good approximations to the
truth.
In order to obtain the other oxide, Berzelius digests mercury in a
solution of the supermuriate of platina; a black powder is thrown down,
which is found to be platina, and mercury is taken up, being oxidized
at the expence of the platina. It was found that 16.7 grains of mercury
had precipitated 8.5 of platina; and the mercury being calculated as
in the state of deutoxide, contained, from the known proportions of
this metal, 1.4 oxygen; hence 8.5 platina must have yielded 1.4 oxygen;
and if 8.5 ∶ 1.4 ∷ 100 ∶ 16.4; so that 100 platina must have had
16.4 oxygen in the supermuriate, or twice the quantity it had in the
insoluble muriate.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account