A new system of chemical philosophy, Volume 2, Part 1 — John Shaqi
A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
This conclusion appears to me premature; the mercurial oxide should at
least have been precipitated and a corresponding quantity have been
found and proved to be the red oxide. Even had this been the case,
it is not easy to determine what quantity of it might be due to the
residue of nitro-muriatic acid. But I have not found that the common
yellow or red oxide of mercury is precipitated by lime water in such
case; the precipitate is brown, and evidently contains both mercury and
platina. Proust had found in his excellent essay on platina (Journ. de
Physique 52--437, 1801) that mercury decomposes muriate of platina,
that an amalgam of platina with a little calomel, and much mercury
in powder, were precipitated; exposed to heat, a fine black powder
was left which had the characters of platina. Into a solution of pure
platina that had been evaporated to dryness in 150° and redissolved,
I put 9¼ grs. of mercury, and boiled it for 10 minutes in a glass
capsule, till there was apparently no further change; the liquor
filtered was as yellow as at first; the mixture of black powder and
running mercury remaining on the filter, when dried, weighed 6½ grains;
this heated to a low red in an iron spoon, left 1 grain of fine black
powder; the liquid saturated with lime water, yielded 2½ grains dry
black powder insoluble in cold nitric acid; after this, protomuriate of
tin threw down 5¾ grains of the compound oxides of platina and tin. The
solution at first contained 3.3 grains of platina.
In another experiment 2 parts of calomel were put to 1 of platina in
solution; when heated to boiling, the calomel was dissolved and a
little black powder was precipitated, which did not amount to half
the weight of the platina. Lime water threw down from the liquid,
a yellowish olive or brown precipitate, partially soluble in cold
nitro-muriatic acid; and after this, muriate of tin yielded a brown
precipitate. These experiments shew that the action between muriate of
platina and mercury or the mercurial salts, is of a complicated nature,
and is not limited to the decomposition of the oxide of platina and the
substitution of the deutoxide of mercury in its place.
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