A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
The difficulties abovementioned have led me to investigate the oxygen
combining with platina by means of the nitrous gas yielded upon its
solution in nitro-muriatic acid. By three distinct experiments I found
that 10 grains of pure platina by solution yielded nearly 750 grain
measures of nitrous gas, which may be considered as 1 grain in weight;
⅞ of which = .875 for oxygen; this would give 8.75 oxygen per cent. But
from a subsequent experiment made under circumstances calculated to
preclude as much as possible every source of fallacy, I obtained 790
measures of nitrous gas from 10 grains of platina; and the solution
afterwards took 60 measures of oxymuriatic acid gas before a permanent
smell of the gas was produced. These 790 measures = 1.05 grain, ⅞
of which = .92, to which add .04 for the oxygen acquired from the
oxymuriatic acid, and we have .96 oxygen for 10 platina; or 100 platina
take 9.6 oxygen. But if 9.6 ∶ 100 ∷ 7 ∶ 73, for the weight of an atom
of platina, and 80 for that of the protoxide, as I apprehend it to be,
and the only oxide of platina we can at present form. (The atom of
platina in Vol. 1, page 248, was estimated at 100.)
3. _Oxide of Silver._
When silver wire is exploded by electricity in oxygen gas, a black
powder is produced, which is the oxide of silver. If silver be
dissolved in nitric acid and precipitated by lime water, an olive
brown powder falls which becomes black when exposed to the light. This
black powder is the only oxide of silver with which we are acquainted.
The proportion of silver and oxygen has been investigated by various
chemists; the results are as under.
silver oxygen
Wenzel 100 + 8.5
Proust + 9.5
Bucholz and Rose + 9.5[2]
Gay Lussac + 7.6[3]
Berzelius + 7.925
[Footnote 2: 7.9 when duly corrected. Annal. de Chimie, 78--114.]
[Footnote 3: Memoirs d’Arcueil 2--168.]
From the solution of 170 grains of standard silver I obtained nearly 30
oz. measures of nitrous gas = 18½ grains, corresponding to 16 oxygen.
This would give 9.4 oxygen upon 100 silver. But as ⅒ of the metal or 17
grains was copper, and this takes ¼ of its weight of oxygen, we shall
have 159 silver and 11¾ oxygen, or 100 silver and 7.7 oxygen nearly.
If we adopt 7.8 as the proper quantity of oxygen on 100 silver, we
shall have 7.8 ∶ 100 ∷ 7 ∶ 90 nearly, which represents the weight of an
atom of silver, and 97 that of the oxide.
4. _Oxides of Mercury._
Two oxides of mercury have been long known and are well distinguished
from each other. They may be obtained by exposing mercury to a heat not
exceeding 600°, in contact with oxygen gas or atmospheric air, and due
agitation; but this method is rarely adopted in practice. A high degree
of heat decomposes the oxides again.
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