A new system of chemical philosophy, Volume 2, Part 1 — John Shaqi
A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
_Protoxide._ To obtain the protoxide, mercury must be slowly dissolved
in dilute nitric acid without heat, and an excess of mercury must be
used. If to 1000 grain measures of nitric acid, 1.2 sp. gr. be put 500
grains of mercury, by occasional agitation the requisite solution will
be obtained in 24 hours. A portion of this solution must be treated
with a small excess of lime water or caustic alkali, when a black
powder will be thrown down, which is the oxide containing a minimum of
oxygen, and hence may be considered the protoxide.
_Deutoxide._ If to 1000 measures of nitric acid, 1.2 sp. gr. be put
350 grains of mercury, and the mixture be boiled till the mercury
disappear, a solution will be obtained containing the deutoxide. A
portion of this being treated as beforementioned with lime water, a
yellowish red powder is precipitated, which is the oxide of mercury
containing a maximum of oxygen; all the later authors agree that it
contains just double the quantity of oxygen to a given portion of
mercury that the former does, and may therefore be called the deutoxide.
These two oxides combine with most acids and form salts, some of which
exhibit remarkable differences occasioned by the oxides; thus, muriatic
acid with the protoxide forms protomuriate of mercury, commonly called
_calomel_, an insoluble salt; with the deutoxide it forms deutomuriate
of mercury, commonly called _corrosive sublimate_, a soluble salt.
The proportions of metal and oxygen in the two oxides may be found by
precipitating a known weight of mercury reduced by solution to either
of the oxides, then drying and weighing the oxides, when the increase
of weight by the addition of oxygen may be observed. This method is
less accurate with regard to mercury than to other metals, on account
of the very great weight of the atom, by which a small error in the
gross weight of the oxide will be a great one as it respects the
oxygen. This circumstance will partly account for the differences of
authors on this subject.
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