A Practical Handbook on the Distillation of Alcohol from Farm ProductsWright, F. B. (Frederic B.)
Science
A Practical Handbook on the Distillation of Alcohol from Farm Products
Wright, F. B. (Frederic B.)
Alcohol; Alcohol, Denatured
A glance at this table shows to what an extent an alcoholic liquor may be
strengthened by distillation, and how the quantity of spirit in the
distillate increases in proportion as that contained in the original
liquor diminishes. It will also be seen that successive distillations of
spirituous liquors will ultimately yield a spirit of very high strength.
As an example, suppose that a liquid containing five per cent, of alcohol
is to be distilled. Its vapor condensed gives a distillate containing 42
per cent. of alcohol which, if re-distilled, affords another containing
82 per cent. This, subjected again to distillation, yields alcohol of
over 90 per cent. in strength. Thus three successive distillations have
strengthened the liquor from five per cent. to 90 per cent.
It will thus be clear that the richness in alcohol of the vapors given
off from boiling alcoholic liquids is not a constant quantity, but that
it necessarily diminishes as the ebullition is continued. For example a
liquor containing seven per cent. of alcohol yields, on boiling a vapor
containing 50 per cent. The first portion of the distillate will,
therefore, be of this strength. But as the vapor is proportionally richer
in alcohol, the boiling liquor must become gradually weaker, and, in
consequence, must yield weaker vapors. Thus, when the proportion of
alcohol in the boiling liquid has sunk to five per cent., the vapors
condensed at that time will contain only 40 per cent.; at two per cent.
of alcohol in the liquor, the vapors yield only 28 per cent., and at one
per cent., they will be found when condensed to contain only 13 per cent.
From this it will be understood that if the distillation be stopped at
any given point before the complete volatilization of all the alcohol the
distillate obtained will be considerably stronger than if the process had
been carried on to the end. Moreover, another advantage derived from
checking the process before the end, and keeping the last portions of the
distillate separate from the rest, besides that of obtaining a stronger
spirit, is that a much purer one is obtained also. The volatile,
essential oils, mentioned above, are soluble only in strong alcohol, and
insoluble in its aqueous solutions. They distill also at a much higher
temperature than alcohol, and so are found only among the last products
of the distillation, which results from raising the temperature of the
boiling liquid. This system of checking the distillation and removing the
products at different points is frequently employed in the practice of
rectification.
CHAPTER III.
DISTILLING APPARATUS.
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