Acids, Alkalis and SaltsAdlam, George Henry Joseph
Science
Acids, Alkalis and Salts
Adlam, George Henry Joseph
Acids; Alkalies; Salts
This operation, when carried out in a chemical laboratory, is a very
simple one. Fig. 4 shows the necessary apparatus. Sulphur dioxide from a
siphon of the liquefied gas and air from a gasholder are passed into the
Woulff’s bottle A, containing concentrated sulphuric acid; this removes
moisture from the gases. The drying process is completed in the tower B,
which contains pumice stone soaked in sulphuric acid. The mixed gases
then pass through the tube C, containing platinized asbestos heated to
about 400° C.: the sulphur trioxide collects in the cooled receiver D.
[Illustration: Fig. 4. SULPHUR TRIOXIDE—THE CONTACT PROCESS]
Platinized asbestos is made by soaking long-fibred asbestos in a
solution of platinum chloride. The material is then dried and subjected
to a gentle heat. In this way, metallic platinum in an exceedingly fine
state of subdivision is deposited on the asbestos fibre, which merely
serves as a convenient support.
Catalytic or Contact Action. The influence of the finely divided
platinum is a very important factor in the reaction. It cannot, however,
be said to _cause_ the union of sulphur dioxide with oxygen, for the
gases combine to a very slight extent when it is not present. What the
platinum actually does is to influence the rate of formation to such a
degree that, under favourable conditions, practically the whole of the
sulphur dioxide is changed to sulphur trioxide instead of an exceedingly
small fraction of it.
The most interesting, and at the same time the most perplexing, feature
of the reaction is that the platinum itself does not appear to undergo
any change. It is not diminished in quantity, for only a very small
amount is necessary for the conversion of a very large amount of the
mixed gases. Its activity lasts for a very long time, and even when it
does become inactive, it can be shown that this is due to some external
cause, such as the presence of dust and certain impurities in the gases.
Many other similar cases are known in which the presence of a small
quantity of a third substance greatly influences the course of a
chemical reaction without appearing in any other way to be necessary to
the reaction. These substances, which are often metals in a very fine
state of subdivision, are called catalytic or contact agents.
The Contact Process for making sulphuric acid is nothing more nor less
than the simple laboratory operation which we have described above,
carried out on a larger scale.
Public-domain text, read in full here on John Shaqi.
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