Acids, Alkalis and SaltsAdlam, George Henry Joseph
Science
Acids, Alkalis and Salts
Adlam, George Henry Joseph
Acids; Alkalies; Salts
Propellants. Although combustion is propagated through a quantity of
gunpowder with very great rapidity, it is not done instantaneously. The
time required is about one-hundredth of a second under ordinary
conditions, and this interval, short though it is, is very important.
When the object is to throw a projectile, the inertia of the latter has
to be overcome, that is, a certain amount of force has to be applied
before the heavy body begins to move. In order that the strain on the
breech of the gun may be as small as possible, the pressure must be
gradually developed and must reach its maximum just as the projectile
begins to move.
The time factor in the explosion constitutes the difference between what
we now call “propellants” and “high explosive.” Propellants are
explosives which develop pressure gradually, and are therefore used to
launch the projectile; high explosive develops pressure instantaneously,
and is therefore used as the bursting charge inside the shell, bomb, or
torpedo, and also in blasting operations.
Cordite, or smokeless powder, is the propellant now most used. It is
made by macerating guncotton and nitroglycerine with their common
solvent acetone. A pulp is thus made to which 5 per cent. of vaseline is
added. The mixture is then forced through a die, and in this way it is
formed into threads or rods, which harden as the acetone evaporates.
Cordite produces no smoke, because all the products of its combustion
are invisible gases.
High Explosive. _Nitroglycerine_ and _Guncotton_ are both explosives of
the instantaneous kind. The former is made by forcing glycerine, under
pressure in a very fine stream, into a mixture of fuming nitric and
concentrated sulphuric acids; the latter by soaking cotton-wool in a
similar mixture. Both products are washed with water until quite free
from acid, and subsequently dried.
Nitroglycerine is a colourless oil with a burning taste. The oil itself
is very dangerous to handle, for it is liable to explode spontaneously
even when the utmost care has been taken in its preparation. A mere spot
on a filter paper explodes with a deafening report when gently hammered
on an anvil; and one drop, when heated on a stout iron plate, blows a
hole through the plate. No use could be made of this substance for many
years after its discovery because it was so liable to explode during
transportation; now, however, it is made safer by mixing with absorbent
infusorial earth or _kieselguhr_. This mixture is known as dynamite.
Blasting gelatine, like cordite, is a mixture of nitroglycerine and
guncotton.
Public-domain text, read in full here on John Shaqi.
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