Acids, Alkalis and SaltsAdlam, George Henry Joseph
Science
Acids, Alkalis and Salts
Adlam, George Henry Joseph
Acids; Alkalies; Salts
The gases coming from the pans in which the salt was decomposed were led
into towers (see Fig. 8) built of bricks or Yorkshire flags soaked in
tar. These towers were filled up with coke or other acid-resisting
material, which was kept moist by water flowing from the tank F. In this
way, hydrogen chloride gas was removed and hydrochloric acid collected
in tanks (not shown in the figure) at the bottom of the towers. Even
then, there was no market for the greater part of the recovered acid,
consequently much of it found its way into drains and streams, and so
carried on its work of destruction in a less obtrusive way.
[Illustration: Fig. 8. PREPARATION OF HYDROCHLORIC ACID]
By another piece of legislation, which at first sight seems to be wholly
unconnected with Chemistry, hydrochloric acid acquired a greatly
enhanced value. In 1861, the tax on paper was removed, and in the next
twenty years the demand for that commodity increased so much that raw
material both cheaper and more abundant than rag had to be found.
Esparto grass and eventually wood pulp proved successful substitutes.
There is really very little difference in composition between cotton and
linen rag on the one hand and wood fibre on the other, for both are
mainly composed of cellulose, which is a definite chemical compound.
Wood fibre is the less pure, and it is also coloured, and therefore has
to be bleached before it can be used for making white paper. It was this
circumstance which led to the greatly increased demand for hydrochloric
acid.
At the beginning of this chapter, it was mentioned, in passing, that
hydrogen chloride gas is a compound of hydrogen and chlorine. The latter
element is a very active bleaching agent, and is most easily obtained by
treating hydrogen chloride or its solution in water with pyrolusite
(black oxide of manganese), whereby the hydrogen is oxidized, forming
water, and chlorine gas is set free. Being a gas, chlorine is not
convenient to handle in large quantities; it is, therefore, converted
into bleaching powder, commonly but wrongly called chloride of lime.
Bleaching Powder. The manufacture of bleaching powder is carried out in
the following way. Slaked lime to the depth of 3 or 4 in. is spread over
the floor of a special chamber which can be made gas-tight. The lime is
raked up into ridge and furrow, and the chamber is filled with chlorine.
At the end of about twenty-four hours, the greater part of this chlorine
will have been absorbed by the lime. The chamber is then opened, the
lime is raked over to expose a fresh surface, and the process of
chlorination is repeated. Generally this is sufficient; the bleaching
powder should then contain about 35 per cent. of available chlorine.
Public-domain text, read in full here on John Shaqi.
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