Acids, Alkalis and SaltsAdlam, George Henry Joseph
Science
Acids, Alkalis and Salts
Adlam, George Henry Joseph
Acids; Alkalies; Salts
Borax, the best known salt of boric acid, is used in laundry work and
also for making some enamels, for when it is strongly heated it loses
water, and ultimately melts down to a clear “glass” in which the oxides
of metals will dissolve, yielding transparent substances which are
beautifully coloured according to the nature of the oxide used. This
property is often made use of in chemical analysis in what is known as
the “borax-bead” test.
[Illustration: Fig. 9. BORIC ACID]
Boric acid is a natural product; the method by which it is obtained is
of some interest, because it is so simple, and because it shows how mere
traces can be gradually accumulated until a very fair total is
ultimately obtained. Moreover, the method is copied directly from
Nature.
In the early years of the nineteenth century, certain jets of natural
steam, called _suffioni_, which issue from the earth in Tuscany, were
found to contain the vapour of boric acid. These jets of steam are of
volcanic origin. The quantity of boric acid in the vapour is very small
indeed; nevertheless, by the method which is adopted, it can be
profitably recovered, and more than a ton of the solid is daily
produced.
In the same country there are many lagoons, the water of which contains
boric acid. It was rightly conjectured that this boric acid came from
jets of steam which issued from the earth in the bed of the lagoon. This
suggested the idea of building up an artificial lagoon around a group of
jets.
Series of about five of these collecting basins (Fig. 9) are formed,
each one at a slightly lower level than the one which precedes it. The
first basin is filled with water from an adjacent spring, and this is
allowed to remain for twenty-four hours. A sluice is then opened and the
liquid contained in the first basin flows down to the second, where it
remains for another day, and so on until it reaches the last basin of
the series. The liquid by this time is almost fully charged with boric
acid, but it contains only about 2 per cent., because the acid is so
sparingly soluble in water.
From the last basin (A), the liquid runs into large vats (B, D), where
the suspended impurities settle down. The solution of boric acid is then
concentrated by causing it to flow over a broad inclined plane made of
corrugated lead or through a series of shallow vessels heated by jets of
natural steam. The hot liquid flows into another vat (C), and, as it
cools, boric acid crystallizes out and is removed by perforated ladles.
The mother liquor from which the crystals have been withdrawn is, of
course, a cold saturated solution of the acid, and this is returned to
the top of the incline to flow down again and lose more water. The boric
acid is finally transferred to drying chambers, which are also heated by
the natural steam.
Public-domain text, read in full here on John Shaqi.
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