Acids, Alkalis and SaltsAdlam, George Henry Joseph
Science
Acids, Alkalis and Salts
Adlam, George Henry Joseph
Acids; Alkalies; Salts
Aluminium Acetate, made by dissolving alumina in acetic acid, is the
“red liquor” which is used as a mordant in dyeing. It is a colourless
liquid, but is called “red liquor” because it is used with dyes which
give a red colour.
Ferrous Acetate, made in a similar way from scrap iron and acetic acid,
is the “black liquor” used in dyeing.
Verdigris, or basic copper acetate, is a valuable pigment. It is made by
interposing cloths soaked in vinegar between plates of copper. After the
action has been allowed to go on for a long time, the plates are washed
with water and the verdigris is scraped off. The finest verdigris is
made in France in the wine-producing district around Montpellier. Here,
instead of cloths soaked in vinegar, the solid residue from the wine
presses is spread in layers between the copper plates. The product made
in this way is called _vert de Montpellier_.
[Illustration: Fig. 11. DUTCH PROCESS FOR WHITE LEAD]
Verdigris, like all the copper compounds, is extremely poisonous. It is
very liable to be formed on the surface of copper utensils used for
cooking purposes.
Lead Acetate, or sugar of lead, is used in large quantities in the
colour industry for making various reds and yellows. It is prepared by
dissolving the metal or its oxide (litharge) in acetic acid.
The slow action which acetic acid vapour has upon the metal lead finds a
very interesting application in what is known as the Dutch process for
the manufacture of white lead[4] for paint. The metal is cast into grids
or spirals, which are placed on the shoulders of the specially made pots
sketched in Fig. 11. A little dilute acetic acid is poured into each of
the pots, which are then arranged side by side on a thick layer of tan
bark, stable manure, or other material which will heat by fermentation.
The first layer of pots is then boarded over; another layer of pots is
placed upon this, and so on, tier upon tier, until the shed is quite
full. The heat developed by the fermenting material vaporizes the acetic
acid, and this vapour corrodes the lead, forming basic lead acetate. The
carbon dioxide which is also produced during fermentation converts the
acetate into the carbonate, which falls as a heavy white powder into the
pots.
Future Supply of Acetic Acid. When all the operations involved in the
production of acetic acid from wood, from the felling of the tree to the
final separation of the glacial substance, are taken into consideration,
it will be readily understood how it is that this acid has never been
cheap when compared with other acids used on an equally large scale. In
addition to this, the competition for wood for paper-making and for the
very numerous cellulose industries is rapidly increasing. It is,
therefore, not surprising to learn that chemists have turned their
attention towards the discovery of newer and cheaper methods of making
acetic acid.
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