Acids, Alkalis and SaltsAdlam, George Henry Joseph
Science
Acids, Alkalis and Salts
Adlam, George Henry Joseph
Acids; Alkalies; Salts
Alkalis. Wood ashes were valued in very early times because they were
found to be good for removing dirt from the skin. Mixed with vegetable
oil or animal fat, they formed a very primitive kind of soap, which was
afterwards much improved by using the aqueous extract instead of the
ashes themselves, and also by the addition of a little caustic lime.
When plant ashes are treated with water, about 10 per cent. dissolves.
If the insoluble matter is then allowed to settle down and the clear
liquid evaporated to dryness, a whitish residue is obtained. The soluble
matter thus extracted from the ashes of plants which grow in or near the
sea is mainly soda; that from land plants, mainly potash. Formerly no
distinction was made, and the general term “alkali” was applied to both.
In order to bring the properties of alkalis into contrast with those of
acids, we cannot do better than make a few simple experiments with a
weak solution of washing soda. Its taste is very different from that of
an acid; it is generally described as caustic. If a little is rubbed
between the fingers, it feels smooth, almost like very thin oil. It does
not dissolve metals or limestone. Its action on vegetable colouring
matter is just as striking as that of acids. Tincture of red cabbage
becomes green; the purple of litmus is changed to a light blue. This
colour change is characteristic of alkalis.
Neutralization. When the colour of litmus solution has been changed to
red by the addition of an acid, the original colour can be restored by
adding an alkali. The change can be repeated as often as desired by
adding acid and alkali alternately. From this we get a distinct
impression of antithesis between the two. In popular language, an alkali
“kills” an acid; in Chemistry, the same idea is expressed by the term
“neutralization.”
Salts. Both “neutralization” and “killing the acid” are modes of
expression which describe the phenomenon fairly well. When an acid is
neutralized, its characteristic taste, its solvent power, and its action
on litmus, are all changed; in fact, the acid as an acid ceases to
exist, and so does the alkali. When the neutral solution is evaporated
to dryness, a residue is found which on examination proves to be neither
the acid nor the alkali, but a compound formed from the two. This
substance is called a salt.
To most people, salt is the name for that particular substance which is
taken as a condiment with food. Its use in this connection dates from
time immemorial. It is distinctly unfortunate that another and very much
wider usage of the term has been introduced into Chemistry. When the
early chemists recognized that other substances, which they vaguely
designated as “saline bodies,” were similar to common salt in
composition, they took the name of the individual and applied it to the
whole class.
OTHER METHODS OF SALT FORMATION
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