Acids, Alkalis and SaltsAdlam, George Henry Joseph
Science
Acids, Alkalis and Salts
Adlam, George Henry Joseph
Acids; Alkalies; Salts
Electricity is employed in chemical industry in two ways. In the first
place, it may be used to produce very high temperatures required for the
reduction of some metallic ores, for melting highly-refractory
substances, and for making steel. It is, however, rather with the second
method, called electrolysis, that we are here mainly concerned.
[Illustration: Fig. 15. THE ELECTROLYSIS OF SALT SOLUTION]
Solutions of acids, bases, and salts, and in some cases the fused
substances themselves, conduct the electric current; but at the same
time they suffer decomposition. This method of decomposing a substance
is known as _electrolysis_, or a breaking up by the agency of
electricity.
The apparatus required in a very simple case is shown in Fig. 15. It
merely consists of some suitable vessel to contain the liquid; two
plates—one to lead the current into the solution, the other to lead it
away again—and wires to connect the plates to the poles of a battery,
storage-cell, or dynamo. Each plate is called an _electrode_, and
distinguished as positive or negative according as it is joined to the
positive or negative pole of the current generator. By convention,
electricity is supposed to “flow” from the positive pole of the battery
to the positive electrode or _anode_, and then through the solution to
the negative electrode or _cathode_, and so back to the negative pole of
the generator, thus completing the circuit external to the battery.
When acids, alkalis, and salts are dissolved in water, there is strong
evidence to show that they break up to a greater or less extent into at
least two parts called _ions_. These are atoms, or groups of atoms,
which have either acquired or lost one or more _electrons_.[5] They move
about quite independently of one another and in any direction until the
electrodes are placed in the liquid. Then they are constrained to move
in two opposing streams—those which have acquired electrons all move
towards the negative electrode, and those which have lost electrons
towards the other. At the electrodes themselves, the former give up and
the latter take up electrons, and become atoms again. Let us now
consider a concrete example. Common salt is composed of atoms of sodium
and atoms of chlorine paired. When a small quantity of this substance is
dissolved in a large quantity of water, the pairing no longer obtains.
The chlorine atoms move away independently accompanied by an extra
satellite or electron, and the sodium atoms move away also but with
their electron strength one below par. When the current is introduced
into the liquid, the sodium ions travel towards the cathode and chlorine
ions towards the anode, and when they reach the goal, sodium ions gain
one electron and chlorine ions lose one, and both become atoms again.
Chlorine atoms combine in pairs forming molecules and escape from the
solution in the greenish yellow cloud that we call chlorine gas. The
Public-domain text, read in full here on John Shaqi.
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