He thus not only nearly forestalled Dalton’s atomic theory, but also our
recent work on the stereometric orientation of the atoms in the molecule
in a crystal structure. Dalton’s full theory was not published until the
year 1811, in his epoch-making book entitled “A New System of Chemical
Philosophy,” although his first table of atomic weights was given as an
appendix to the memoir of 1803. Thus in the days when chemistry was in
the making at the hands of Priestley, Lavoisier, Cavendish, and Dalton
do we find that crystallography was so intimately connected with it that
a crystallographer well-nigh forestalled a chemist in the first real
epoch-making advance, a lesson that the two subjects should never be
separated in their study, for if either the chemist or the
crystallographer knows but little of what the other is doing, his work
cannot possibly have the full value with which it would otherwise be
endowed.
The basis of Haüy’s conceptions was undoubtedly cleavage. He describes
most graphically on page 10 of his “Essai” of 1784 how he was led to
make the striking observation that a hexagonal prism of calcite,
terminated by a pair of hexagons normal to the prism axis, similar to
the prisms shown in Fig. 6 (Plate III.) except that the ends were flat,
showed oblique internal cleavage cracks, by enhancing which with the aid
of a few judicious blows he was able to separate from the middle of the
prism a kernel in the shape of a rhombohedron, the now well-known
cleavage rhombohedron of calcite. He then tried what kinds of kernels he
could get from dog-tooth spar (illustrated in Fig. 7) and other
different forms of calcite, and he was surprised to find that they all
yielded the same rhombohedral kernel. He subsequently investigated the
cleavage kernels of other minerals, particularly of gypsum, fluorspar,
topaz, and garnet, and found that each mineral yielded its own
particular kernel. He next imagined the kernels to become smaller and
smaller, until the particles thus obtained by cleaving the mineral along
its cleavage directions _ad infinitum_ were the smallest possible. These
miniature kernels having the full composition of the mineral he terms
“_Molécules Constituantes_” in the 1784 “Essai,” but in the 1801
“Traité” he calls them “_Molécules Intégrantes_” as above mentioned. He
soon found that there were three distinct types of _molécules
intégrantes_, tetrahedra, triangular prisms, and parallelepipeda, and
these he considered to be the crystallographic structural units.
[Illustration:
FIG. 12.
]
Public-domain text, read in full here on John Shaqi.
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