Detection of the Common Food AdulterantsBruce, Edwin M.
Science
Detection of the Common Food Adulterants
Bruce, Edwin M.
Food adulteration and inspection
SALICYLIC ACID
(This is not often used as a preservative of milk.)
_Leach suggests the following method for its detection._--Dissolve one
gram of mercury in 2 grams of nitric acid (sp. gr. 1.42) and then add to
the solution the same volume of water. Add 1 cc. of this reagent to 50
cc. of the milk to be tested, and shake and filter. The perfectly clear
filtrate is shaken with ether and the ether extract evaporated to
dryness. Then add a drop of ferric chlorid solution, and a violet color
will be produced if salicylic acid is present.
BUTTER
Butter is often colored with annatto, saffron, turmeric, marigold or
coal-tar colors. By a certain process, stale or old butter is sometimes
worked over and made to appear fresh for a time. This is sold under the
name of “process” or “renovated” butter. Foreign fats like cottonseed
oil, sesame oil, or oleomargarine may be substituted for or added to
pure butter.
COLORING MATTER
_Martin’s Test._--Add 2 parts of carbon bisulfid, a little at a time and
with frequent shaking, to 15 parts of alcohol. Shake 25 cc. of this
solution with 5 grams of the butter, and let stand for some time. The
carbon bisulfid dissolves out the fatty matter and settles to the
bottom. The alcohol remains on top and will dissolve out any artificial
colors that may be present. If only a little coloring matter is present
use more of the butter.
ANNATTO
Evaporate a portion of the extract to dryness and add sulfuric acid to
the residue. If annatto is present a greenish-blue color forms. Should a
pink tint result the presence of a coal-tar color is to be suspected.
COAL-TAR COLORS
These colors will dye wool or silk if pieces of the fiber are boiled in
the diluted alcoholic extract, which has first been acidified with
hydrochloric acid. The normal butter coloring matter will not dissolve
when thus treated.
_Geisler’s Method._--To a few drops of the clarified fat on a porcelain
surface, add a very little fullers’ earth. If a pink to violet-red
coloration is produced in a short time the presence of an azo-color is
indicated.
SAFFRON
When saffron is present, nitric acid colors the alcoholic extract green,
and hydrochloric acid colors it red.
TURMERIC
Add ammonia to the alcoholic extract, and if it turns brown it indicates
the presence of turmeric.
MARIGOLD
Add silver nitrate to the extract, and if it turns black the presence of
marigold is indicated.
PROCESS OR RENOVATED BUTTER
Heat a little of the suspected butter in a spoon or dish, and if it is
process butter it will sputter, but not foam much. Make the test also
with some butter known to be pure and fresh.
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