Dyes and dyeingPellew, Charles E. (Charles Ernest), Viscount Exmouth
Science
Dyes and dyeing
Pellew, Charles E. (Charles Ernest), Viscount Exmouth
Dyes and dyeing
For dyeing by the Vat method the dye-pot is two-thirds filled with
warm water, at about 120° F. (when the finger can hardly bear the
heat), and one or two tablespoonfuls of caustic soda are added—enough
to make the bath decidedly alkaline. The dyestuff, preferably first
mixed up with some hot water, to thin the paste, is stirred into the
liquid, and then to this is added sodium hydrosulphite, in powder, or
preferably dissolved in water, until the color of the bath changes
from blue, first to green, and then to greenish yellow, with a
bluish-green coppery scum. If the bath is bright yellow, too much
hydrosulphite has been used, and some more indigo should be added;
or, if this is not desirable for fear of getting too dark shades, the
bath should be exposed to the air and stirred frequently until the
color is right. If the bath, on scraping aside the scum, looks blue,
or even markedly green, it needs a little more hydrosulphite. If,
after reduction, the bath looks yellow but turbid, it probably needs
more alkali.
Into this bath the material is placed, and stirred around until
thoroughly saturated—the temperature being kept about 120° F. for
heavy goods, to assist penetration. Light goods can be dyed equally
well in a lukewarm, or even a cold bath. The goods are then taken
out, wrung lightly by hand, and are carefully passed two or three
times through the wringer, to get the color evenly distributed. They
are then shaken out and hung up in the air to oxidize. In fifteen or
twenty minutes, after the color has changed, they should be rinsed
well in two or three waters, to get rid of all traces of the caustic
alkali, and then boiled for several minutes in a soap bath, to wash
off the loose dyestuff and prevent rubbing. This after-treatment with
boiling soapsuds is of even more importance in the case of the other
Vat dyes than it is with indigo, for with most of them the oxidation
is not completed in the air—and so the color is developed as well as
brightened by the soap bath.
It is very important, when working with these Vat colors, to remember
that hot solutions of caustic alkali are very hard on the hands
and that, therefore, rubber gloves are extremely useful, if not
essential. Stains left on hands, clothes, and utensils, although
difficult to remove by washing, are almost instantly dissolved by
warm solutions of hydrosulphite with a little soda or other alkali in
them.
Public-domain text, read in full here on John Shaqi.
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