Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The combination is known to be perfect, that is, the Point of
Saturation is known to be obtained, when, after repeated affusions of
an Acid in small quantities to an Alkali, or an absorbent earth, we
find those phenomena cease, which in such cases constantly attend the
conflict of union, as we said above, namely, ebullition, hissing, _&c._
and we may be assured the Saturation is complete when the new compound
hath neither an acid nor an acrid taste, nor in the least changes the
blue colours of vegetables.
Neutral salts have not so great an affinity with water as either Acids
or Alkalis have; because they are more compounded: for we observed
before, that the affinities of the most compounded bodies are generally
weaker than those of the most simple. In consequence hereof few Neutral
Salts, when dried, attract the moisture of the air; and those that do,
attract it more slowly, and in less quantity, than either Acids or
Alkalis do.
All Neutral Salts are soluble in water; but more or less readily, and
in a greater or smaller quantity, according to the nature of their
component principles.
Water made boiling hot dissolves a greater quantity of those salts
which do not attract the moisture of the air, than when it is cold;
and indeed it must be boiling hot to take up as much of them as it
is capable of dissolving: but as for those which run in the air, the
difference, if there be any, is imperceptible.
Some Neutral Salts have the property of shooting into crystals, and
others have it not.
The nature of Crystallization is this: Water cannot dissolve, nor keep
in solution, more than a determinate quantity of any particular Salt:
when therefore such a quantity of water is evaporated from the solution
of a Salt capable of crystallization, that the remainder contains just
as much Salt as it can dissolve, then by continuing the evaporation
the Salt gradually recovers its solid form, and concretes into several
little transparent masses called Crystals. These crystals have regular
figures, all differing from one another according to the species of
salt of which they are formed. Different methods of evaporating saline
solutions have different effects on the figure and regularity of the
crystals; and each particular sort of salt requires a peculiar method
of evaporation to make its crystals perfectly regular.
A solution of salt designed for crystallization is usually evaporated
by means of fire to a pellicle; that is, till the Salt begin to
concrete; which is perceived by a kind of thin dark skin that gathers
on the surface of the liquor, and is formed of the crystallized
particles of Salt. When this pellicle appears the solution is suffered
to cool, and the crystals form therein faster or slower, according to
the sort of salt in hand. If the evaporation be carried on briskly to
perfect dryness, no crystals will be formed, and only an irregular mass
of salt will be obtained.
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