Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The reasons why no crystals appear when the evaporation is hastily
performed, and carried on to dryness, are, first, that the particles
of salt, being always in motion while the solution is hot, have not
time to exert their mutual affinities, and to unite together as
crystallization requires: Secondly, that a certain quantity of water
enters into the very composition of crystals; which is therefore
absolutely necessary to their formation, and in a greater or smaller
proportion according to the nature of the Salt[1].
[1] Those who have the curiosity to see a more particular account
of the Crystallization of Neutral Salts, may read Mr. _Rouelle_'s
excellent Memoir on that subject, among those of the Academy of
Sciences for 1744.
If these crystallized salts be exposed to the fire, they first part
with that moisture which is not necessary to a saline concretion, and
which they retained only by means of their crystallization: afterwards
they begin to flow, but with different degrees of fusibility.
It must be observed, that certain salts melt as soon as they are
exposed to the fire; namely, those which retain a great deal of water
in crystallizing. But this fluor which they so readily acquire must be
carefully distinguished from actual fusion: for it is owing only to
their superfluous humidity, which heat renders capable of dissolving
and liquifying them; so that when it is evaporated the Salt ceases to
be fluid, and requires a much greater degree of fire to bring it into
real fusion.
The Neutral Salts that do not crystallize may, indeed, be dried by
evaporating the water which keeps them fluid; but by becoming solid
they acquire no regular form; they again attract the moisture of
the air, and are thereby melted into a liquor. These may be called
_Liquescent Salts_.
Most of the Neutral Salts, that consist of an Acid joined with a fixed
Alkali, or with an absorbent earth, are themselves fixed and resist
the force of fire; yet several of them, if they be dissolved in water,
and the solution boiled and evaporated, fly off along with the steams.
CHAP. IV.
_Of the several Sorts of Saline Substances._
SECTION I.
_Of the_ UNIVERSAL ACID.
The Universal Acid is so called, because it is in fact the Acid which
is most universally diffused through all nature, in waters, in the
atmosphere, and in the bowels of the earth. But it is seldom pure;
being almost always combined with some other substance. That from which
we obtain it with most ease, and in the greatest quantity, is Vitriol,
a mineral which we shall consider afterwards: and this is the reason
why it is called the _Vitriolic Acid_; the name by which it is best
known.
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