Elements of the Theory and Practice of Chymistry, 5th ed. — John Shaqi
Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
When the Vitriolic Acid contains but little phlegm, yet enough to give
it a fluid form, it is called _Oil of Vitriol_, on account of a certain
unctuosity belonging to it. In truth this name is very improperly
bestowed on it; for we shall afterwards see that, bating this
unctuousness, it has none of the properties of oils. But this is not
the only impropriety in names that we shall have occasion to censure.
If the Vitriolic Acid contain much water, it is then called _Spirit of
Vitriol_. When it does not contain enough to render it fluid, and so is
in a solid form, it is named the _Icy Oil of Vitriol_.
When Oil of Vitriol highly concentrated is mixed with water, they rush
into union with such impetuosity, that, the moment they touch each
other, there arises a hissing noise, like that of red-hot iron plunged
in cold water, together with a very considerable degree of heat,
proportioned to the degree to which the Acid was concentrated.
If, instead of mixing this concentrated Acid with water, you only
leave it exposed to the air for some time, it attracts the moisture
thereof, and imbibes it most greedily. Both its bulk and its weight are
increased by this accession; and if it be under an icy form, that is,
if it be concreted, the phlegm thus acquired will soon resolve it into
a fluid.
The addition of water renders the Vitriolic Acid, and indeed all other
Acids, weaker in one sense; which is, that when they are very aqueous
they leave on the tongue a much fainter taste of acidity, and are less
active in the solution of some particular bodies: but that occasions
no change in the strength of their affinities, but in some cases
rather enables them to dissolve several substances, which, when well
dephlegmated, they are not capable of attacking.
The Vitriolic Acid combined to the point of saturation with a
particular absorbent earth, the nature of which is not yet well known,
forms a Neutral Salt that crystallizes. This Salt is called _Alum_, and
the figure of its crystals is that of an octahedron, or solid of eight
sides. These octahedra are triangular pyramids, the angles of which are
so cut off that four of the surfaces are hexagons, and the other four
triangles.
There are several sorts of Alum, which differ according to the earths
combined with the Vitriolic Acid. Alum dissolves easily in water, and
in crystallization retains a considerable quantity of it; which is the
reason that being exposed to the fire it readily melts, swelling and
puffing up as its superfluous moisture exhales. When that is quite
evaporated, the remainder is called _Burnt Alum_, and is very difficult
to fuse. The Acid of the Alum is partly dissipated by this calcination.
Its taste is saltish, with a degree of roughness and astringency.
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