other materials, and is stored for use in covered wooden compartments
situated in or near the mixing rooms, along with the other materials
which may be used in the glass mixtures.
Footnote 2:
_See_ “British Glass Sands” (Boswell), “British Glassmaking Sands”
(Peddle); papers read at the third meeting, Society of Glass
Technology, Sheffield, for further information.
The alkalies, potash or soda, or a mixture of both, are commonly used in
making glass in the form either of carbonates, sulphates, or nitrates.
The soda and potash silicates form very fusible glasses, but they are
not permanent, being soluble in water; therefore they cannot be used
alone. In making glassware for domestic use, other bases, such as lead
oxide, barium, or lime, have to be added to form more insoluble
combinations with the silica or sand.
=Carbonate of Potash= or =Pearlash=, which before the war was imported
into this country by glass makers from Stassfurt, is much prized by
crystal glass makers on account of the colourless silicate it forms when
fused with the best white sand. It is now very expensive and difficult
to get, and is less used on this account. Potash carbonate is very
hygroscopic and absorbs much moisture from the air; therefore it is
necessary to keep it within sealed chests while in store.
Potash and soda each have an influence upon the colour of the resulting
glasses in which they are respectively used. The potash silicate gives
better and clearer glasses than the soda silicate.
=Carbonate of Soda=, or =Soda Ash=, is now more generally used. Being a
less expensive form of alkali, it constitutes a base in most of the
commoner varieties of glassware. Carbonate of soda is manufactured in
England from common salt, of which there are large deposits in the
Midlands. This common salt, or chloride of sodium, is treated chemically
and converted into the carbonate, in which form it is supplied to the
glass manufacturers as soda ash.
=Sulphate of Soda= (=Salt Cake=) is the form of alkali used in window
and bottle glassmaking. In mixtures containing sulphate of soda it is
necessary to use a small proportion of carbon in some form, such as
charcoal or coal, in order to assist the decomposition of the salt and
the formation of the sodium silicate. Sulphate of soda is used in this
class of glassware on account of its cheapness. Glasses made from
sulphate of soda mixtures are not so clear and colourless as those in
which the source of alkali is potash or soda carbonate. On this account,
the best crystal glasses cannot be made from sulphate of soda.
=Potash Nitrate= (=Saltpetre=) is used in glass mixtures to oxidise the
molten metal and improve the colour of the glass. In fusing it
disengages oxygen gas, which purifies the glass while melting, and
assists the decolorizers in their action by keeping up an oxidising
condition within the molten mass.
Public-domain text, read in full here on John Shaqi.
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