Illustrations of Universal Progress: A Series of DiscussionsSpencer, Herbert
Philosophy
Illustrations of Universal Progress: A Series of Discussions
Spencer, Herbert
Philosophy; Political science; Science
There is every reason to believe that at an extreme heat the elements
cannot combine. Even under such heat as can be artificially produced, some
very strong affinities yield, as for instance, that of oxygen for hydrogen;
and the great majority of chemical compounds are decomposed at much lower
temperatures. But without insisting upon the highly probable inference,
that when the Earth was in its first state of incandescence there were no
chemical combinations at all, it will suffice our purpose to point to the
unquestionable fact that the compounds that can exist at the highest
temperatures, and which must, therefore, have been the first that were
formed as the Earth cooled, are those of the simplest constitutions. The
protoxides--including under that head the alkalies, earths, &c.--are, as a
class, the most stable compounds we know: most of them resisting
decomposition by any heat we can generate. These, consisting severally of
one atom of each component element, are combinations of the simplest
order--are but one degree less homogeneous than the elements themselves.
More heterogeneous than these, less stable, and therefore later in the
Earth's history, are the deutoxides, tritoxides, peroxides, &c.; in which
two, three, four, or more atoms of oxygen are united with one atom of metal
or other element. Higher than these in heterogeneity are the hydrates; in
which an oxide of hydrogen, united with an oxide of some other element,
forms a substance whose atoms severally contain at least four ultimate
atoms of three different kinds. Yet more heterogeneous and less stable
still are the salts; which present us with compound atoms each made up of
five, six, seven, eight, ten, twelve, or more atoms, of three, if not more,
kinds. Then there are the hydrated salts, of a yet greater heterogeneity,
which undergo partial decomposition at much lower temperatures. After them
come the further-complicated supersalts and double salts, having a
stability again decreased; and so throughout. Without entering into
qualifications for which we lack space, we believe no chemist will deny it
to be a general law of these inorganic combinations that, _other things
equal_, the stability decreases as the complexity increases.
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