Weld, which is often used, is rich in oxidizable principles; it turns
sour, and passes into the putrid fermentation with facility. Some
dyers use it very freely; but ordinarily we employ in this bath an
equal quantity of it to that of the bran. Sometimes weld is not added
at all.
In most dye-houses the pastel is pounded before introducing it into
the vat. Some practical men, however, maintain that this operation is
injurious, and that it interferes with its durability. This is an
opinion which deserves attention. The effect of the pastel, when
reduced to a coarse powder, is more uniform; but this state of
division must render its alterations more rapid. When the bath has
undergone the necessary ebullition, the pastel should be introduced
into the vat, the liquor decanted, and at the same time 7 or 8 lbs. of
lime added, so as to form an alkaline lye which shall hold the indigo
in solution. Having well stirred the vat, it should be set aside for
four hours, so that the little pellets shall have time to become
thoroughly soaked, both inside and out, and thus be prepared for
fermentation. Some think coverings are to be spread over the vat, so
as to preserve it from contact with the atmosphere. After this lapse
of time, it is to be again stirred. The bath at this moment presents
no decided character; it has the peculiar odor of the vegetables which
it holds in digestion; its color is of a yellowish-brown.
Ordinarily, at the end of twenty-four hours, sometimes even after
fifteen or sixteen, the fermentative process is well marked. The odor
becomes ammoniacal, at the same time that it retains the peculiar
smell of the pastel. The bath, hitherto of a brown color, now assumes
a decided yellowish-red tint. A blue froth, which results from the
newly liberated indigo of the pastel, floats on the liquor as a thick
scum, being composed of small blue bubbles, which are closely
agglomerated together. A brilliant pellicle covers the bath, and
beneath we may perceive some blue or almost black veins, owing to the
indigo of the pastel which rises towards the surface. If the liquor be
now agitated with a switch, the small quantity of indigo which is
evolved floats to the top of the bath. On exposing a few drops of this
mixture to the air, the golden-yellow color quickly disappears, and is
replaced by the blue tint of the indigo. This phenomenon is due to the
absorption of the oxygen of the air by the indigogen from the pastel:
in this state we might even dye wool with it without any further
addition of indigo; but the colors which it furnishes are devoid of
brilliancy and vivacity of tone, at the same time that the bath
becomes quickly exhausted.
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