On adipocire, and its formationWetherill, Charles Mayer
Science
On adipocire, and its formation
Wetherill, Charles Mayer
Adipocere; Fatty acids; Postmortem changes
The fat from Liquid melts solidifies
1^o 36°-46° 41°-?
2^o 39°-41° 37°-35.5°
4^o[6] 59°-62° 40.5°-35°
5^o 62°-66° 58°-53°
6^o 53°-56° 41°-?
The melting point of liquid 2^o, does not accord with that above
stated, but I note the experiments as they were observed, merely
mentioning that I observed carefully, and am not conscious of having
made an error. The above points seem vague, but it was impossible to
fix a point definitely, as a cloudiness persisted up to the highest
degree stated, so I prefer to give the limits of certainty. In 1^o and
6^o the solidifying points, 41°, were taken when the liquid in the
capillary tubes seemed to become solid, but it remained translucent
for a long time below this point, and 6^o only became opaque (and that
gradually) when suffered to stand in the air.
We are reminded here of Duffy’s observations upon certain isomeric
transformations of the fats, (Quar. Jour. Ch. Sec. V. 197.) He
noticed that stearine heated 1° above its point of solidification,
became transparent, but soon after resumed its opacity; and Heintz
made a similar observation. Duffy attributes this to an isomeric
transformation of the fat by the heat; but it seems to me simpler until
an isomerism be more distinctly proven, to assume a mixture of fats,
which unite to form a definite compound under the circumstances, and
which has the above mentioned property.[7] Heintz’s researches on the
fats should make us look with suspicion upon fats as pure, that are
only purified by crystallization.
Duffy’s remarks were made upon the glycerine compounds of the
fatty acids; it appears from the above examination of the liquids
1^o and 6^o, as if something similar took place with the fatty
acids themselves, although, with one or two exceptions, in other
determinations of melting points noted in this article, I have not
observed the same phenomenon of transparency.
Public-domain text, read in full here on John Shaqi.
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