Pigments, Paint and Painting: A practical book for practical men — John Shaqi
Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
_Yellow Prussiate._--The first step is the preparation of the yellow
prussiate of potash. The manufacture of this substance, although
an industry of considerable importance, is comparatively little
understood, either from a scientific or a practical point of view. At
all events, many prussiate makers seem completely at sea with regard
to the most favourable conditions for carrying on the manufacture, and
there can be no doubt that in many cases great waste occurs, through
ignorance of the various reactions which take place during the process.
The raw materials usually consist of carbonate of potash, iron filings
or turnings, and organic matters containing carbon and nitrogen--such
as dried blood, woollen rags, horn, hair, leather scraps, &c. The
most suitable substances for use are, of course, those containing the
largest proportion of nitrogen. The following are the percentages of
nitrogen in various kinds of animal matter:--
Horn 15 to 17
Dried blood 15 to 17
Woollen rags 10 to 16
Sheep shearings 16 to 17
Calves’ hair 15 to 17
Bristles 9 to 10
Feathers 16 to 17
Hide clippings 4 to 5
Old shoes 6 to 7
Horn charcoal 2 to 7
Rag charcoal 2 to 12
Animal matters always contain more carbon than is necessary for the
formation of cyanogen by combining with the nitrogen also present.
Consequently, when such substances are heated with pearlash, the
excess of carbon reduces a portion of the carbonate to the metallic
state, and this potassium combines with the cyanogen to produce
potassium cyanide. The manufacture of yellow prussiate of potash may
be conveniently divided into three stages: (1) The production of the
molten mass technically known as “metal”; (2) the lixiviation; and (3)
the crystallisation.
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