When the industrial sample, more or less voluminous, reaches the
laboratory, the chemist is to begin by taking a note of the marks,
labels, and descriptions found thereon, and of the nature and state of
the package which contains it, and the date of its arrival. All this
information should be entered upon the laboratory book and afterwards
transcribed on the paper containing the results of the analysis, as
well as the name of the person sending it. This having been done, the
sample is to be properly prepared in order that a portion may be taken
representing exactly the mean composition of the whole.
If it is in a state of fine powder, such as ground phosphates and
certain other fertilizers, it is sufficient to pass it two or three
times through a sieve with meshes one millimeter in diameter, taking
care to break up the material each time in order to mix it and
to pulverize the fragments which the sieve retains. The whole is
afterwards spread in a thin layer upon a large sheet of paper, and a
portion is taken here and there upon the point of a knife until about
twenty grains are removed, and from this the portion subjected to
analysis is afterwards taken.
If the sample comes in fragments, more or less voluminous, such as
phosphatic rocks or coarsely pulverized guanos containing agglomerated
particles, it is necessary first to reduce the whole to powder by
rubbing it in a mortar or in a small drug mill. It is next passed
through a sieve of the size mentioned above and that which remains upon
the sieve pulverized anew until all has passed through. This precaution
is very important, since the parts which resist the action of the
pestle the most have often a composition different from those which are
easily broken.
When the products to be analyzed contain organic materials, such as
horn, flesh, dry blood, etc., the pulverization is often a long and
difficult process, and results in a certain degree of heating which
drives off some of the moisture in such a way that the pulverized
product is at the last drier, and, consequently, richer than the
primitive sample. It is important to take account of this desiccation,
and since the pulverization of a mass so voluminous can not be made
without loss, the determination of the total weight of the sample
before and after pulverization does not give exact results.
In such a case it is indispensable to determine the moisture, both
before and after pulverizing, and to calculate the analytical results
obtained upon the pulverized sample back to the original sample.
Public-domain text, read in full here on John Shaqi.
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